|Table of Contents|

REE Mineralization Promoted by Crustal Contamination in Mianning-Dechang REE Metallogenic Belt, the Western Sichuan, China(PDF)

《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

Issue:
2024年第05期
Page:
636-650
Research Field:
基础地质与矿床地质
Publishing date:

Info

Title:
REE Mineralization Promoted by Crustal Contamination in Mianning-Dechang REE Metallogenic Belt, the Western Sichuan, China
Author(s):
SI Yuan-long1; 2;  ZHAO Yun1; 2*;  WANG Rui2; 3;  ZHOU Li-min4;  SUN Ying-cai2; 3;  WANG Jun-da1; 2;  ZHU Zhi-min5
(1. School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China; 2. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China; 3. Institute of Earth Sciences, China University of Geosciences, Beijing 100083, China; 4. National Research Center for Geoanalysis, Beijing 100037, China; 5. Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences, Chengdu 610041, Sichuan, China)
Keywords:
carbonatite-related REE deposit;  Re-Os isotope;  metallogenic age;  crustal contamination;  precipitation mechanism;  Mianning-Dechang REE metallogenic belt;  Sichuan
PACS:
P618.7; P597
DOI:
10.19814/j.jese.2023.12026
Abstract:
The Mianning-Dechang REE metallogenic belt in the western Sichuan is the most important REE belts in China. Nevertheless, the relationship between crustal contamination and REE mineralization remains elusive. The Re-Os isotopic signatures of molybdenite have been widely applied for tracing crustal contamination. In order to reveal the influence of crustal contamination on carbonatite-related REE mineralization, the Re-Os isotopic composition of molybdenite was studied in Maoniuping and Muluozhai REE deposits. Molybdenite occurs in calcite interstice in magmatic stage, or occurs in quartz interstice in pegmatite stage, or intergrows with hydrothermal minerals(fluorite, barite, bastnäsite)and sulfide(pyrite, galena)in hydrothermal stage. The Re-Os model ages of molybdenite in Maoniuping REE deposit are dated at 25.93 and 26.05 Ma, and the Re contents are 44.933×10-6 and 28.678×10-6, respectively. The Re-Os model age of molybdenite in Muluozhai REE deposit is dated at 28.90 Ma, and the Re content is 38.765×10-6. The formation age of molybdenite is consistent with the diagenesis and mineralization age of REE deposit, indicating that molybdenite precipitation and REE mineralization occur simultaneously. The Re content of three molybdenite samples are in the level of 10-5, indicating a crust-mantle mixing affinity. The contamination neutralizes the pH of REE-bearing fluid, which lead to the instability of REE-chloride and REE-sulfate. The mixing of molybdenum-bearing fluid increases the concentration of CO2-3 in the fluid and promotes the precipitation of bastnäsite.

References:

[1] HOU Z Q,MA H W,KHIN Z,et al.The Himalayan Yulong Porphyry Copper Belt:Product of Large-scale Strike-slip Faulting in Eastern Tibet[J].Economic Geology,2003,98(1):125-145.
[2] HOU Z Q,COOK N J.Metallogenesis of the Tibetan Collisional Orogen:A Review and Introduction to the Special Issue[J].Ore Geology Reviews,2009,36(1/2/3):2-24.
[3] 谢玉玲,夏加明,崔 凯,等.中国碳酸岩型稀土矿床:时空分布与成矿过程[J].科学通报,2020,65(33):3794-3808.
XIE Yu-ling,XIA Jia-ming,CUI Kai,et al.Rare Earth Elements Deposits in China:Spatio-temporal Distribution and Ore-forming Processes[J].Chinese Science Bulletin,2020,65(33):3794-3808.
[4] 袁忠信,施泽民,白 鸽,等.四川冕宁牦牛坪轻稀土矿床[M].北京:地震出版社,1995.
YUAN Zhong-xin,SHI Ze-min,BAI Ge,et al.The Maoniuping Rare Earth Ore Deposit in Mianning County,Sichuan Province[M].Beijing:Seismological Pre-ss,1995.
[5] HOU Z Q,LIU Y,TIAN S H,et al.Formation of Carbonatite-related Giant Rare-earth-element Deposits by the Recycling of Marine Sediments[J].Scientific Reports,2015,5:10231.
[6] TIAN S H,HOU Z Q,SU A N,et al.The Anomalous Lithium Isotopic Signature of Himalayan Collisional Zone Carbonatites in Western Sichuan,SW China:Enriched Mantle Source and Petrogenesis[J].Geochimica et Cosmochimica Acta,2015,159:42-60.
[7] WENG Q,YANG W B,NIU H C,et al.B-Sr-Nd-Pb Isotopic Constraints on the Origin of the Maoniuping Alkaline Syenite-carbonatite Complex,SW China[J].Ore Geology Reviews,2021,135:104193.
[8] 田世洪,侯增谦,袁忠信,等.四川冕宁木落寨稀土矿床成岩成矿的40Ar/39Ar年代学研究[J].岩石学报,2006,22(10):2431-2436.
TIAN Shi-hong,HOU Zeng-qian,YUAN Zhong-xin,et al.40Ar/39Ar Geochronology of Rocks and Ores from the Muluozhai REE Deposit in Mianning County,Sichuan Province[J].Acta Petrologica Sinica,2006,22(10):2431-2436.
[9] 田世洪,侯增谦,杨竹森,等.川西冕宁—德昌REE成矿带成矿年代学研究:热液系统维系时限和构造控矿模型约束[J].矿床地质,2008,27(2):177-187.
TIAN Shi-hong,HOU Zeng-qian,YANG Zhu-sen,et al.Geochronology of REE Deposits in Mianning-Dechang REE Metallogenic Belt:Constraints on Duration of Hydrothermal Activities and Tectonic Model for Carbonatite-alkalic Complexes in Southwestern Sichuan[J].Mineral Deposits,2008,27(2):177-187.
[10] 田世洪,侯增谦,杨竹森,等.四川大陆槽稀土矿床碳酸岩-英碱正长岩锆石U-Pb年代学和Hf同位素性质及其地质意义[J].岩石学报,2008,24(3):544-554.
TIAN Shi-hong,HOU Zeng-qian,YANG Zhu-sen,et al.Zircon U-Pb Ages,Hf Isotopic Compositions,and Geological Significance:A Case Study of Carbonatite and Nordmarkite from the Dalucao REE Deposit,Sichuan Province[J].Acta Petrologica Sinica,2008,24(3):544-554.
[11] 胡文洁,田世洪,王素平,等.四川牦牛坪稀土矿床碳酸岩Sm-Nd等时线年龄及其地质意义[J].矿产与地质,2012,26(3):237-241.
HU Wen-jie,TIAN Shi-hong,WANG Su-ping,et al.Sm-Nd Isochron Age of Carbonatite from the Maoniu-ping REE Deposit,Sichuan Province and Their Geological Implications[J].Mineral Resources and Geology,2012,26(3):237-241.
[12] LIU Y,CHEN Z Y,YANG Z S,et al.Mineralogical and Geochemical Studies of Brecciated Ores in the Dalucao REE Deposit,Sichuan Province,Southwestern China[J].Ore Geology Reviews,2015,70:613-636.
[13] LING X X,LI Q L,LIU Y,et al.In-situ SIMS Th-Pb Dating of Bastnaesite:Constraint on the Mineralization Time of the Himalayan Mianning-Dechang Rare Earth Element Deposits[J].Journal of Analytical Atomic Spectrometry,2016,31(8):1680-1687.
[14] LIU Y,HOU Z Q,ZHANG R Q,et al.Zircon Alteration as a Proxy for Rare Earth Element Mineralization Processes in Carbonatite-nordmarkite Complexes of the Mianning-Dechang Rare Earth Element Belt,China[J].Economic Geology,2019,114(4):719-744.
[15] 付浩邦,刘 琰,郑 旭,等.川西木落寨稀土矿床年代学、地球化学与成矿特征[J].矿床地质,2019,38(3):491-508.
FU Hao-bang,LIU Yan,ZHENG Xu,et al.Geochronology,Geochemistry and Metallogenic Characteristics of Muluozhai Deposit in Southwestern Sichuan Province[J].Mineral Deposits,2019,38(3):491-508.
[16] JIA Y H,LIU Y.Factors Controlling the Generation and Diversity of Giant Carbonatite-related Rare Earth Element Deposits:Insights from the Mianning-De-chang Belt[J].Ore Geology Reviews,2020,121:103472.
[17] HOU Z Q,TIAN S H,YUAN Z X,et al.The Himalayan Collision Zone Carbonatites in Western Sichuan,SW China:Petrogenesis,Mantle Source and Tectonic Implication[J].Earth and Planetary Science Letters,2006,244(1/2):234-250.
[18] LIU Y,CHAKHMOURADIAN A R,HOU Z Q,et al.Development of REE Mineralization in the Giant Mao-niuping Deposit(Sichuan,China):Insights from Mi-neralogy,Fluid Inclusions,and Trace-element Geochemistry[J].Mineralium Deposita,2019,54(5):701-718.
[19] ZHENG X,LIU Y.Mechanisms of Element Precipitation in Carbonatite-related Rare-earth Element Depo-sits:Evidence from Fluid Inclusions in the Maoniu-ping Deposit,Sichuan Province,Southwestern China[J].Ore Geology Reviews,2019,107:218-238.
[20] ZHENG X,LIU Y,ZHANG L S.The Role of Sulfate-,Alkali-,and Halogen-rich Fluids in Mobilization and Mineralization of Rare Earth Elements:Insights from Bulk Fluid Compositions in the Mianning-Dechang Carbonatite-related REE Belt,Southwestern China[J].Lithos,2021,386/387:106008.
[21] ANENBURG M,BROOM-FENDLEY S,CHEN W.Formation of Rare Earth Deposits in Carbonatites[J].Elements,2021,17(5):327-332.
[22] XIE Y L,HOU Z Q,YIN S P,et al.Continuous Carbonatitic Melt-fluid Evolution of a REE Mineralization System:Evidence from Inclusions in the Maoniu-ping REE Deposit,Western Sichuan,China[J].Ore Geology Reviews,2009,36(1/2/3):90-105.
[23] XIE Y L,LI Y X,HOU Z Q,et al.A Model for Carbonatite Hosted REE Mineralisation:The Mianning-Dechang REE Belt,Western Sichuan Province,China[J].Ore Geology Reviews,2015,70:595-612.
[24] SHU X C,LIU Y,LI D L.Contrasting Composition of Two Biotite Generations in the Lizhuang Rare-earth Element Deposit,Sichuan Province,Southwestern China[J].Geological Journal,2020,55(12):7638-7658.
[25] WENG Q,YANG W B,NIU H C,et al.Formation of the Maoniuping Giant REE Deposit:Constraints from Mineralogy and In-situ Bastnäsite U-Pb Geochronology[J].American Mineralogist,2022,107(2):282-293.
[26] WENG Q,NIU H C,QU P,et al.Mica Compositional Constraints on the Petrogenesis and Mineralization of the Syenite-carbonatite Complex in the Maoniuping REE Deposit,SW China[J].Ore Geology Reviews,2022,145:104917.
[27] LI S L,ZHANG W,CAI J L,et al.Multiple Pulses of Fluids Involved in the Formation of Carbonatite-rela-ted REE Deposits as Revealed by Fluorite[J].Ore Geology Reviews,2023,159:105546.
[28] 刘 琰,舒小超.碳酸岩型稀土矿床中的霓长岩化作用概述[J].矿物岩石地球化学通报,2021,40(5):1025-1033.
LIU Yan,SHU Xiao-chao.An Overview of Fenitization in Carbonatite-related Rare Earth Element Deposits[J].Bulletin of Mineralogy,Petrology and Geochemistry,2021,40(5):1025-1033.
[29] 舒小超,刘 琰,李德良,等.川西冕宁—德昌稀土矿带霓长岩的地球化学特征及地质意义[J].岩石学报,2019,35(5):1372-1388.
SHU Xiao-chao,LIU Yan,LI De-liang,et al.Geochemical Characteristics and Geological Significance of Fenites in the Mianning-Dechang REE Belt,Western Sichuan Province[J].Acta Petrologica Sinica,2019,35(5):1372-1388.
[30] WENG Q,YANG W B,NIU H C,et al.Two Discrete Stages of Fenitization in the Lizhuang REE Deposit,SW China:Implications for REE Mineralization[J].Ore Geology Reviews,2021,133:104090.
[31] HOU Z Q,TIAN S H,XIE Y L,et al.The Himalayan Mianning-Dechang REE Belt Associated with Carbo-natite-alkaline Complexes,Eastern Indo-Asian Collision Zone,SW China[J].Ore Geology Reviews,2009,36(1/2/3):65-89.
[32] 翁 强,牛贺才,杨武斌,等.川西碱性岩-碳酸岩型稀土矿床成矿模型[J].矿物岩石地球化学通报,2022,41(3):465-473.
WENG Qiang,NIU He-cai,YANG Wu-bin,et al.The Metallogenic Model of Alkaline Rocks-carbonatite Related REE Deposits in the Western Sichuan,China[J].Bulletin of Mineralogy,Petrology and Geoche-mistry,2022,41(3):465-473.
[33] YUAN X Y, YANG Z M, MAYANOVIC R A,et al.Experimental Evidence Reveals the Mobilization and Mineralization Processes of Rare Earth Elements in Carbonatites[J].Science Advances,2024,10(27):eadm9118.
[34] 陈 超.川西大陆槽隐爆角砾岩型稀土矿床成因浅析[D].北京:中国地质大学,2018.
CHEN Chao.Brief Analysis About Generation of Dalucao Rare-earth Deposit of Cryptoexplosive Breccia Type in Western Sichuan Province[D].Beijing:China University of Geosciences,2018.
[35] 向 蜜.川西牦牛坪碳酸岩-煌斑岩成因关系:Li-Ca同位素制约[D].南昌:东华理工大学,2022.
XIANG Mi.Genetic Relationship Between Carbonatites-lamprophyres in Maoniuping,Western Sichuan:Li-Ca Isotopic Evidence[D].Nanchang:East China University of Technology,2022.
[36] BELL K,TILTON G R.Probing the Mantle:The Story from Carbonatites[J].Eos,2002,83(25):273-277.
[37] 欧阳怀.四川木落寨稀土矿床地质特征与成因探讨[D].北京:中国地质大学,2019.
OUYANG Huai.Geological Characteristics and Genesis of the Muluozhai REE Deposit in Sichuan Province[D].Beijing:China University of Geosciences,2019.
[38] 姜 恒.川西木落寨稀土矿床郑家梁子矿段地质特征与成因研究[D].北京:中国地质大学,2018.
JIANG Heng.Study on Geological Characteristics and Genesis of the Zhengjialiangzi Ore Block in Muluozhai REE Deposit,Sichuan Province[D].Beijing:China University of Geosciences,2018.
[39] ZHENG X,LIU Y,SMITH M P,et al.Carbonatitic Magma Fractionation and Contamination Generate Rare Earth Element Enrichment and Mineralization in the Maoniuping Giant REE Deposit,SW China[J].Journal of Petrology,2023,64(6):egad037.
[40] FOSTER J G,LAMBERT D D,FRICK L R,et al.Re-Os Isotopic Evidence for Genesis of Archaean Nickel Ores from Uncontaminated Komatiites[J].Nature,1996,382:703-706.
[41] STEIN H J,SUNDBLAD K,MARKEY R J,et al.Re-Os Ages for Archean Molybdenite and Pyrite,Kuittila-Kivisuo,Finland and Proterozoic Molybdenite,Kabeliai,Lithuania:Testing the Chronometer in a Metamorphic and Metasomatic Setting[J].Mineralium Deposita,1998,33(4):329-345.
[42] MAO J W,ZHANG Z C,ZHANG Z H,et al.Re-Os Isotopic Dating of Molybdenites in the Xiaoliugou W(Mo)Deposit in the Northern Qilian Mountains and Its Geological Significance[J].Geochimica et Cosmochimica Acta,1999,63(11/12):1815-1818.
[43] LAMBERT D D,FOSTER J G,FRICK L R,et al.Re-Os Isotopic Systematics of the Voisey's Bay Ni-Cu-Co Magmatic Ore System,Labrador,Canada[J].Lithos,1999,47(1/2):69-88.
[44] STEIN H J,MARKEY R J,MORGAN J W,et al.Re-Os Dating of Boddington Molybdenite,SW Yilgarn:Two Au Mineralization Events[C]∥CASSIDY K F,DUNPHY J M,VAN KRANENDONK M J.International Archaean Symposium.Canberra:AGSO,2001:469-471.
[45] STEIN H J,MARKEY R J,MORGAN J W,et al.The Remarkable Re-Os Chronometer in Molybdenite:How and Why It Works?[J].Terra Nova,2001,13(6):479-486.
[46] XU C,KYNICKY J,CHAKHMOURADIAN A R,et al.A Unique Mo Deposit Associated with Carbonatites in the Qinling Orogenic Belt,Central China[J].Lithos,2010,118(1/2):50-60.
[47] 王登红,陈毓川,徐 珏,等.中国新生代成矿作用[M].北京:地质出版社,2005.
WANG Deng-hong,CHEN Yu-chuan,XU Jue,et al.Cenozoic Mineralization in China[M].Beijing:Geolo-gical Publishing House,2005.
[48] XIE Y L,VERPLANCK P L,HOU Z Q,et al.Rare Earth Element Deposits in China:A Review and Some New Understandings[M]∥CHANG Z S,GOLDFARB R J.Mineral Deposits of China.Littleton:Society of Economic Geologists,2019:509-552.
[49] GUO Z F,HERTOGEN J,LIU J Q,et al.Potassic Magmatism in Western Sichuan and Yunnan Provin-ces,SE Tibet,China:Petrological and Geochemical Constraints on Petrogenesis[J].Journal of Petrology,2005,46(1):33-78.
[50] WANG J H,YIN A,HARRISON T M,et al.A Tectonic Model for Cenozoic Igneous Activities in the Eastern Indo-Asian Collision Zone[J].Earth and Pla-netary Science Letters,2001,188(1/2):123-133.
[51] 张玉泉,谢应雯.哀牢山—金沙江富碱侵入岩年代学和Nd,Sr同位素特征[J].中国科学:D辑,地球科学,1997,27(4):289-293.
ZHANG Yu-quan,XIE Ying-wen.Geochronology of Alkali-rich Intrusions and Nd,Sr Isotopic Characteri-stics in Ailao Shan-Jinsha River[J].Science in China:Series D,Earth Sciences,1997,27(4):289-293.
[52] CHUNG S L,LO C H,LEE T Y,et al.Diachronous Uplift of the Tibetan Plateau Starting 40 Myr Ago[J].Nature,1998,394:769-773.
[53] LIU Y,HOU Z Q.A Synthesis of Mineralization Sty-les with an Integrated Genetic Model of Carbonatite-syenite-hosted REE Deposits in the Cenozoic Mianning-Dechang REE Metallogenic Belt,the Eastern Tibetan Plateau,Southwestern China[J].Journal of Asian Earth Sciences,2017,137:35-79.
[54] LIU Y,HOU Z Q,TIAN S H,et al.Zircon U-Pb Ages of the Mianning-Dechang Syenites,Sichuan Province,Southwestern China:Constraints on the Giant REE Mineralization Belt and Its Regional Geological Setting[J].Ore Geology Reviews,2014,64:554-568.
[55] 侯增谦,田世洪,谢玉玲,等.川西冕宁—德昌喜马拉雅期稀土元素成矿带:矿床地质特征与区域成矿模型[J].矿床地质,2008,27(2):145-176.
HOU Zeng-qian,TIAN Shi-hong,XIE Yu-ling,et al.Mianning-Dechang Himalayan REE Belt Associated with Carbonatite-alkalic Complex in Eastern Indo-Asian Collision Zone,Southwest China:Geological Characteristics of REE Deposits and a Possible Metallogenic Model[J].Mineral Deposits,2008,27(2):145-176.
[56] 侯增谦,郑远川,耿元生.克拉通边缘岩石圈金属再富集与金-钼-稀土元素成矿作用[J].矿床地质,2015,34(4):641-674.
HOU Zeng-qian,ZHENG Yuan-chuan,GENG Yuan-sheng.Metallic Refertilization of Lithosphere Along Cratonic Edges and Its Control on Au,Mo and REE Ore Systems[J].Mineral Deposits,2015,34(4):641-674.
[57] 从柏林.攀西古裂谷的形成与演化[M].北京:科学出版社,1988.
CONG Bo-lin.Formation and Evolution of Panxi Paleo-rift[M].Beijing:Science Press,1988.
[58] 张云湘,骆耀南,杨崇喜.攀西裂谷[M].北京:地质出版社,1988.
ZHANG Yun-xiang,LUO Yao-nan,YANG Chong-xi.Panxi Rift[M].Beijing:Geological Publishing House,1988.
[59] WENG Q,NIU H C,QU P,et al.Controlling Factors of Prolonged REE Mineralization in the Maoniuping REE Deposit:Constraints from Alkaline Granite in the Syenite-carbonatite Complex[J].Ore Geology Reviews,2022,142:104705.
[60] 阳正熙,WILLIAMS-JONES A E,蒲广平.四川冕宁牦牛坪稀土矿床地质特征[J].矿物岩石,2000,20(2):28-34.
YANG Zheng-xi,WILLIAMS-JONES A E,PU Guang-ping.Geological Features of Maoniuping REE Depo-sit,Sichuan,China[J].Journal of Mineralogy and Petrology,2000,20(2):28-34.
[61] 胡泽松,沈 冰,朱志敏,等.四川省冕宁县南河乡阴山村方家堡稀土矿区普查报告[R].成都:中国地质科学院矿产综合利用研究所,2008.
HU Ze-song,SHEN Bing,ZHU Zhi-min,et al.Exploration Report of Fangjiabao REE Deposit in Yinshan Village,Nanhe Town,Mianning County,Sichuan Pro-vince[R].Chengdu:Institute of Multipurpose Utilization of Mineral Resources,Chinese Academy of Geological Sciences,2008.
[62] 郑 旭,刘 琰,欧阳怀,等.川西冕宁木落寨碳酸岩型稀土矿床流体演化对成矿的制约:来自包裹体和稳定同位素的证据[J].岩石学报,2019,35(5):1389-1406.
ZHENG Xu,LIU Yan,OUYANG Huai,et al.The Evolution of Ore-forming Fluid Constraints on Minerali-zation of the Muluozhai Carbonatite-related REE Deposit in Western Sichuan:Evidence from Fluid Inclusions and Stable Isotopes[J].Acta Petrologica Sinica,2019,35(5):1389-1406.
[63] LUCK J M,BIRCK J L,ALLEGRE C J.187Re-187Os Systematics in Meteorites:Early Chronology of the Solar System and Age of the Galaxy[J].Nature,1980,283:256-259.
[64] 李 超,屈文俊,杜安道,等.含有普通锇的辉钼矿Re-Os同位素定年研究[J].岩石学报,2012,28(2):702-708.
LI Chao,QU Wen-jun,DU An-dao,et al.Study on Re-Os Isotope in Molybdenite Containing Common Os[J].Acta Petrologica Sinica,2012,28(2):702-708.
[65] 张 鹏,刘珊珊,兰 君,等.山东省微山县郗山稀土矿同位素年代学、岩石地球化学及其成因[J].桂林理工大学学报,2023,43(3):364-377.
ZHANG Peng,LIU Shan-shan,LAN Jun,et al.Isotope Chronology,Petrogeochemistry and Genesis of Chishan REE Deposit in Weishan,Shandong[J].Journal of Guilin University of Technology,2023,43(3):364-377.
[66] 李六权,崔江荣,陈 浩.陕西木龙沟—黄龙铺地区钼、铼、稀土资源量概况及铼、稀土赋存特征[J].陕西地质,2019,37(1):1-7.
LI Liu-quan,CUI Jiang-rong,CHEN Hao.General Situation of Molybdenum,Rhenium and Rare Earth Resources and Occurrence Characteristics of Rhenium and Rare Earth in Mulonggou-Huanglongpu Area of Luonan County[J].Geology of Shaanxi,2019,37(1):1-7.
[67] 于学峰,唐好生,韩作振,等.山东郗山—龙宝山地区与碱性岩有关的稀土矿床地质特征及成因[J].地质学报,2010,84(3):407-417.
YU Xue-feng,TANG Hao-sheng,HAN Zuo-zhen,et al.Geological Characteristics and Origin of Rare Earth Elements Deposits Related with Alkaline Rock in the Chishan-Longbaoshan Area,Shandong Province[J].Acta Geologica Sinica,2010,84(3):407-417.
[68] 张 焱,刘 畅,彭义伟,等.东秦岭黄龙铺矿田桃园Mo矿床成因研究:来自矿物学及辉钼矿Re-Os 同位素的约束[J].矿物岩石,2023,43(1):73-84.
ZHANG Yan,LIU Chang,PENG Yi-wei,et al.Genesis of Taoyuan Mo Deposit in Huanglongpu Ore Fie-ld,East Qinling Mountains:Constraints from Minera-logy and Molybdenite Re-Os Isotope[J].Mineralogy and Petrology,2023,43(1):73-84.
[69] ZHANG W,CHEN W T,GAO J F,et al.Two Episodes of REE Mineralization in the Qinling Orogenic Belt,Central China:In-situ U-Th-Pb Dating of Bast-näsite and Monazite[J].Mineralium Deposita,2019,54(8):1265-1280.
[70] 钟大赉,丁 林,刘福田,等.造山带岩石层多向层架构造及其对新生代岩浆活动制约:以三江及邻区为例[J].中国科学:D辑,地球科学,2000,30(增1):1-8.
ZHONG Da-lai,DING Lin,LIU Fu-tian,et al.The Poly-layered Architecture of Lithosphere in the Orogen and Its Constraint on Cenozoic Magmatism[J].Science in China:Series D,Earth Sciences,2000,30(S1):1-8.
[71] YIN A,HARRISON T M.Geologic Evolution of the Himalayan-Tibetan Orogen[J].Annual Review of Earth and Planetary Sciences,2000,28:211-280.
[72] 莫宣学,赵志丹,邓晋福,等.印度—亚洲大陆主碰撞过程的火山作用响应[J].地学前缘,2003,10(3):135-148.
MO Xuan-xue,ZHAO Zhi-dan,DENG Jin-fu,et al.Response of Volcanism to the India-Asia Collision[J].Earth Science Frontiers,2003,10(3):135-148.
[73] HOU Z Q,WANG Q F,ZHANG H J,et al.Lithosphere Architecture Characterized by Crust-mantle Decoupling Controls the Formation of Orogenic Gold Deposits[J].National Science Review,2023,10(3):nwac257.
[74] HOU Z Q,WANG R,ZHANG H J,et al.Formation of Giant Copper Deposits in Tibet Driven by Tearing of the Subducted Indian Plate[J].Earth-science Reviews,2023,243:104482.
[75] HOU Z Q,XU B,ZHANG H J,et al.Refertilized Continental Root Controls the Formation of the Mianning-Dechang Carbonatite-associated Rare-earth-element Ore System[J].Communications Earth & Environment,2023,4:293.
[76] WALTER B F,GIEBEL R J,STEELE-MACINNIS M,et al.Fluids Associated with Carbonatitic Magma-tism:A Critical Review and Implications for Carbona-tite Magma Ascent[J].Earth-science Reviews,2021,215:103509.
[77] ZHU X X,LIU Y,HOU Z Q.Massive Rare Earth Element Storage in Sub-continental Lithospheric Mantle Initiated by Diapirism,Not by Melting[J].Geology,2024,52(2):105-109.
[78] LIU Y,JING Y T,ZHAO W C.Distribution of Rare Earth Elements and Implication for Ce Anomalies in the Clay-sized Minerals of Deep-sea Sediment,Western Pacific Ocean[J].Applied Clay Science,2023,235:106876.
[79] WENG Q,YANG W B,NIU H C,et al.Sulfur Isotopes of Carbonatite from the Giant Maoniuping REE Deposit,SW China[J].Ore Geology Reviews,2023,162:105694.
[80] 李德良.四川里庄稀土矿床地质特征与成因探讨[D].北京:中国地质大学,2019.
LI De-liang.Geological Characteristics and Genesis of the Lizhuang REE Deposit in Sichuan[D].Beijing:China University of Geosciences,2019.
[81] ZHANG Y,LIU Y,HOU Z Q,et al.Iron and Sulfur Isotopic Compositions of Carbonatite-related REE Deposits in the Mianning-Dechang REE Belt,China:Implications for Fluid Evolution[J].Ore Geology Revi-ews,2021,138:104373.
[82] GIEBEL R J,PARSAPOOR A,WALTER B F,et al.Evidence for Magma-wall Rock Interaction in Carbo-natites from the Kaiserstuhl Volcanic Complex(Southwest Germany)[J].Journal of Petrology,2019,60(6):1163-1194.
[83] ANENBURG M,MAVROGENES J A.Carbonatitic Versus Hydrothermal Origin for Fluorapatite REE-Th Deposits:Experimental Study of REE Transport and Crustal “Antiskarn” Metasomatism[J].American Journal of Science,2018,318(3):335-366.
[84] ANENBURG M,MAVROGENES J A,FRIGO C,et al.Rare Earth Element Mobility in and Around Carbona-tites Controlled by Sodium,Potassium,and Silica[J].Science Advances,2020,6(41):eabb6570.
[85] WALTER B F,GIEBEL R J,SIEGFRIED P R,et al.The Eruption Interface Between Carbonatitic Dykes and Diatremes:The Gross Brukkaros Volcanic Field Namibia[J].Chemical Geology,2023,621:121344.
[86] ZHANG W,CHEN W T,MERNAGH T P,et al.Quantifying the Nature of Ore-forming Fluids in the Dalucao Carbonatite-related REE Deposit,Southwest China:Implication for the Transport and Deposition of REEs[J].Mineralium Deposita,2022,57(6):935-953.
[87] CUI H,ZHONG R C,XIE Y L,et al.Forming Sulfate- and REE-rich Fluids in the Presence of Quartz[J].Geology,2020,48(2):145-148.
[88] MIGDISOV A,WILLIAMS-JONES A E,BRUGGER J,et al.Hydrothermal Transport,Deposition,and Fractionation of the REE:Experimental Data and Thermodynamic Calculations[J].Chemical Geology,2016,439:13-42.
[89] MIGDISOV A A,WILLIAMS-JONES A E.Hydrothermal Transport and Deposition of the Rare Earth Elements by Fluorine-bearing Aqueous Liquids[J].Mineralium Deposita,2014,49(8):987-997.
[90] 黄 凡,王登红,陈毓川,等.中国内生钼矿床辉钼矿的微量元素特征研究[J].矿床地质,2014,33(6):1193-1212.
HUANG Fan,WANG Deng-hong,CHEN Yu-chuan,et al.Trace Elements Characteristics of Molybdenites from Endogenous Molybdenum Deposits in China[J].Mineral Deposits,2014,33(6):1193-1212.
[91] WASTON E B,BRENAN J M,BAKER D R.Distribution of Fluids in the Continental Mantle[C]∥MENZIES M.Oxford Monographs on Geology and Geophysics 16:Continental Mantle.Oxford:Oxford University Press,1990:111-125.
[92] HARMER R E,GITTINS J.The Origin of Dolomitic Carbonatites:Field and Experimental Constraints[J].Journal of African Earth Sciences,1997,25(1):5-28.

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Last Update: 2024-10-01