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Hydrochemical Evolution of Phreatic Water and Variation Characteristics of Nitrogen and Phosphorus Concentrations in Chagan Lake Basin, Northeast China(PDF)

《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

Issue:
2025年第02期
Page:
143-157
Research Field:
水资源与水文地质
Publishing date:

Info

Title:
Hydrochemical Evolution of Phreatic Water and Variation Characteristics of Nitrogen and Phosphorus Concentrations in Chagan Lake Basin, Northeast China
Author(s):
SU Xiao-si1; 2*;  WU Cheng-rong1; 2;  WANG Yong-qi2; 3;  SONG Ya-zhi1; 2;  LI Ning-fei2; 3;  YANG Jing-shuang4;  MA Feng-min4
(1. College of New Energy and Environment, Jilin University, Changchun 130021, Jilin, China; 2. Institute of Water Resources and Environment, Jilin University, Changchun 130021, Jilin, China; 3. College of Construction Engineering, Jilin University, Changchun 130021, Jilin, China; 4. Jilin Chagan Lake National Nature Reserve Administration, Songyuan 131100, Jilin, China)
Keywords:
hydrochemistry;  phreatic water;  nitrogen;  phosphorus;  fuzzy C-mean clustering algorithm;  principal component analysis;  APCS-MLR model;  Northeast China
PACS:
P641.3
DOI:
10.19814/j.jese.2024.10049
Abstract:
In-depth understanding on regional groundwater hydrochemical evolution and its influencing factors, and revealing the sources and causes of nitrogen and phosphorus in the groundwater entering the lake, are of great significance in resolving the contribution of nitrogen and phosphorus discharged into the lake through groundwater and the management of eutrophication in the lake. Chagan lake basin, located in the hinterland of Northeast Plain, was selected as the study area, with particular focus on the Quaternary pore phreatic water that exhibits close hydraulic connectivity to the lake; a comprehensive investigation was conducted by combining the typical regional groundwater flow paths with an integrated analytical framework; hydrogeochemical graphical methods were systematically employed in conjunction with fuzzy C-mean clustering algorithm and principal component analysis(PCA); furthermore, an absolute principal component score-multiple linear regression(APCS-MLR)model was developed to elucidate the spatial evolution patterns of phreatic water hydrochemistry and identify the predominant controlling factors in the study region. The results show that the main chemical type of phreatic water in Chagan lake basin is HCO3-Ca type; total dissolved solids(TDS)and the concentration of main ions in the typical runoff path of phreatic water increase, and the mass concentration ratio of Cl-/Na+ increases; the hydrochemical evolution is mainly controlled by evaporation and concentration, agricultural activities, leaching and cation exchange; Da'an irrigation area in the northern part of the study area is transforming saline-alkali land into paddy field, applying a large amount of fertilizer, the concentrations of nitrogen and phosphorus components in phreatic water increase and the scope expands; saline-alkali land and dry land in the central and western regions are developed into paddy field, the phreatic water environment is partially reduced, and the mass concentration of NH+4 increases; the mass concentrations of NO-3, NH+4 and PO3-4 in phreatic water increase significantly after the transformation of dry land and saline-alkali land into paddy field. The quantitative analysis results based on APCS-MLR model show that the contribution rates of agricultural activities to NH+4, PO3-4 and NO-3 are as high as 87%, 55% and 25%, respectively.

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Last Update: 2025-03-20