|Table of Contents|

Zircon Morphology and Geochemistry Characteristics of Dewulu Intrusive Complex in Gannan Area of Gansu, China and Their Diagenetic Indications(PDF)

《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

Issue:
2025年第02期
Page:
199-215
Research Field:
基础地质与矿床地质
Publishing date:

Info

Title:
Zircon Morphology and Geochemistry Characteristics of Dewulu Intrusive Complex in Gannan Area of Gansu, China and Their Diagenetic Indications
Author(s):
ZHENG Yong-tao12 WANG Shu-zhi12* WANG Tao3 XUN Hao-tian12 TIAN Ying4
(1. School of Emergency Management and Safety Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China; 2. Tangshan Key Laboratory of Geological Resource Development and Disaster Prevention, North China University of Science and Technology, Tangshan 063210, Hebei, China; 3. Chinese Academy of Geological Sciences, Beijing 100037, China; 4. Institute of Regional Geological Survey of Hebei Province, Langfang 065000, Hebei, China)
Keywords:
Au-Cu deposit metallogenic pattern zircon morphology rare earth element mafic microgranular enclave crust-mantle interacting mineralization potential Gansu
PACS:
P572; P612
DOI:
10.19814/j.jese.2024.12016
Abstract:
The Dewulu complex is composed of Dewulu quartz diorite and the Laodou quartz diorite porphyry. The differences between the two plutons in terms of intrusion age and mineralization type indicate that their petrogenesis have important guiding significance for regional mineralization patterns and deep prospecting. The petrogenesis of Dewulu intrusive complex in Gannan area of Gansu and its mafic microgranular enclaves were systematically investigated through statistical analysis of zircon crystal morphology and LA-ICP-MS rare earth element(REE)testing, combined with field observations and petrographic analysis. The results show that Dewulu quartz diorite is more alkali-rich compared to Laodou quartz diorite porphyry, with the chondrite-normalized REE pattern in its zircon exhibiting characteristics of light rare earth element(LREE)depletion and heavy rare earth element(HREE)enrichment, along with a significant positive Ce anomaly(δCe=16.68)and negative Eu anomaly(δEu=0.11); in contrast, Laodou quartz diorite porphyry shows a higher positive(δCe=31.30), and its biotite content(15%-20%)is significantly higher than that of Dewulu quartz diorite(10%-15%), reflecting a more water-rich magma characteristic of Laodou quartz diorite porphyry; the average point distribution and evolutionary trends of typomorphic population in zircon indicates that zircons from both rock types project into a mixed-source calc-alkaline field on zircon classification diagrams, confirming that both have experienced crust-mantle magma mixing processes; the consistency in the chondrite-normalized REE pattern between the inclusions and the host rocks(the contents of REE are(351-628)×10-6)further suggests that they are products of consanguineous magmatic evolution; mineralization potential indicates that the higher oxygen fugacity and water content in Laodou quartz diorite porphyry are more favorable for Au-Cu mineralization, providing important theoretical basis for regional deep mineral exploration.

References:

[1] 贾儒雅,王 涛,李康宁,等.西秦岭德乌鲁含矿岩体及其包体的岩石学成因和构造意义[J].地学前缘,2019,26(5):290-303.
JIA Ru-ya,WANG Tao,LI Kang-ning,et al.Petroge-nesis and Tectonic Implications of the Dewulu Ore-bearing Pluton and Mafic Enclaves in Western Qinling[J].Earth Science Frontiers,2019,26(5):290-303.
[2] 靳晓野,李建威,隋吉祥,等.西秦岭夏河—合作地区德乌鲁杂岩体的侵位时代、岩石成因及构造意义[J].地球科学与环境学报,2013,35(3):20-38.
JIN Xiao-ye,LI Jian-wei,SUI Ji-xiang,et al.Geoch-ronological and Geochemical Constraints on the Genesis and Tectonic Setting of Dewulu Intrusive Complex in Xiahe-Hezuo District of Western Qinling[J].Journal of Earth Sciences and Environment,2013,35(3):20-38.
[3] 李康宁,金鼎国,蔡 龙,等.早子沟金矿黄铁矿标型特征及其地质意义[J].甘肃地质,2014,23(2):33-40.
LI Kang-ning,JIN Ding-guo,CAI Long,et al.Typomorphism and Its Geological Significance of Pyrite in Zaozigou Gold Deposit[J].Gansu Geology,2014,23(2):33-40.
[4] 第鹏飞,汤庆艳,刘 聪,等.西秦岭夏河—合作地区早子沟和加甘滩金矿床石英微量元素特征及意义[J].现代地质,2021,35(6):1608-1621.
DI Peng-fei,TANG Qing-yan,LIU Cong,et al.Trace Element Characteristics of Quartz from the Zaozigou and Jiagantan Gold Deposits in the Xiahe-Hezuo District,West Qinling[J].Geoscience,2021,35(6):1608-1621.
[5] 刘升有.西秦岭北缘德乌鲁矽卡岩型铜矿床地质特征及成矿模式讨论[J].西北地质,2015,48(2):176-185.
LIU Sheng-you.Geological Characteristics and Metallogenic Model of Dewulu Skarn-type Copper Deposits in West Qinling,Gansu Province[J].Northwestern Geology,2015,48(2):176-185.
[6] 黄启富.甘肃以地南金矿床地质特征及控矿因素[J].黄金,2016,37(2):26-29.
HUANG Qi-fu.Geological Characteristics and Ore-controlling Factors of Yidinan Gold Deposit in Gansu[J].Gold,2016,37(2):26-29.
[7] 田向盛,王建飞,赵志成,等.甘肃加甘滩金矿床地质特征及找矿标志[J].甘肃地质,2016,25(1):25-31.
TIAN Xiang-sheng,WANG Jian-fei,ZHAO Zhi-cheng,et al.Geological Characteristics and Prospecting Criteria of Jiagantan Gold Deposit,Gansu[J].Gansu Geo-logy,2016,25(1):25-31.
[8] 李建威,隋吉祥,靳晓野,等.西秦岭夏河—合作地区与还原性侵入岩有关的金成矿系统及其动力学背景和勘查意义[J].地学前缘,2019,26(5):17-32.
LI Jian-wei,SUI Ji-xiang,JIN Xiao-ye,et al.The Intrusion-related Gold Deposits in the Xiahe-Hezuo District,West Qinling Orogen:Geodynamic Setting and Exploration Potential[J].Earth Science Frontiers,2019,26(5):17-32.
[9] 张德贤,束正祥,曹 汇,等.西秦岭造山带夏河—合作地区印支期岩浆活动及成矿作用:以德乌鲁石英闪长岩和老豆石英闪长斑岩为例[J].中国地质,2015,42(5):1257-1273.
ZHANG De-xian,SHU Zheng-xiang,CAO Hui,et al.Indosinian Magmatism and Tectonic Setting of Xiahe-Hezuo Area,Western Qinling Mountains:Implications from the Dewulu Quartz Diorite and Laodou Quartz Dioritic Porphyry[J].Geology in China,2015,42(5):1257-1273.
[10] 杜佰松,申俊峰,秦玉良,等.甘肃省沃尔给花岗岩体中黑云母的成分对其岩体碱度的响应及成岩成矿意义[J].现代地质,2017,31(4):672-682.
DU Bai-song,SHEN Jun-feng,QIN Yu-liang,et al.Chemical Composition of Biotites Responding to Basicity of Wo'ergei Granite Intrusion in Gansu Province and Implications for Petrogenesis and Mineralization[J].Geoscience,2017,31(4):672-682.
[11] RICHARDS J P.Tectono-magmatic Precursors for Porphyry Cu-(Mo-Au)Deposit Formation[J].Economic Geology,2003,98(8):1515-1533.
[12] SILLITOE R H.Porphyry Copper Systems[J].Economic Geology,2010,105(1):3-41.
[13] WANG R,WEINBERG R F,COLLINS W J,et al.Origin of Postcollisional Magmas and Formation of Porphyry Cu Deposits in Southern Tibet[J].Earth-science Reviews,2018,181:122-143.
[14] 王 瑞,朱弟成,王 青,等.特提斯造山带斑岩成矿作用[J].中国科学:地球科学,2020,50(12):1919-1946.
WANG Rui,ZHU Di-cheng,WANG Qing,et al.Porphyry Mineralization in the Tethyan Orogen[J].Science China:Earth Sciences,2020,50(12):1919-1946.
[15] 王 瑞,罗晨皓,夏文杰,等.冈底斯后碰撞斑岩成矿带高水、高氧逸度岩浆成因研究进展[J].矿物岩石地球化学通报,2021,40(5):1061-1077.
WANG Rui,LUO Chen-hao,XIA Wen-jie,et al.Progresses in the Study of High Magmatic Water and Oxidation State of Post-collisional Magmas in the Gangdese Porphyry Deposit Belt[J].Bulletin of Mine-ralogy,Petrology and Geochemistry,2021,40(5):1061-1077.
[16] HOSKIN P W O,SCHALTEGGER U.The Composition of Zircon and Igneous and Metamorphic Petrogenesis[J].Reviews in Mineralogy and Geochemistry,2003,53(1):27-62.
[17] PUPIN J P.Zircon and Granite Petrology[J].Contributions to Mineralogy and Petrology,1980,73(3):207-220.
[18] 廖忠礼,莫宣学,潘桂棠,等.西藏过铝花岗岩锆石群型的成因信息[J].大地构造与成矿学,2006,30(1):63-71.
LIAO Zhong-li,MO Xuan-xue,PAN Gui-tang,et al.Characteristics and Implication of the Topology of Zircons from the Peraluminous Granites in Tibet[J].Geotectonica et Metallogenia,2006,30(1):63-71.
[19] 梁文天.秦岭造山带东西秦岭交接转换区陆内构造特征与演化过程[D].西安:西北大学,2009.
LIANG Wen-tian.Characteristics and Evolutionary Process of Intracontinental Tectonics in the Transferable Conjunction Area of East and West Qinling Mountains of the Qinling Orogenic Belt[D].Xi'an:Northwest University,2009.
[20] 刘春先,李 亮,隋吉祥.甘肃枣子沟金矿的矿化特征及矿床成因[J].地质科技情报,2011,30(6):66-74.
LIU Chun-xian,LI Liang,SUI Ji-xiang.Mineralization Characteristics and Ore Genesis of the Zaozigou Gold Deposit,Gansu Province[J].Geological Science and Technology Information,2011,30(6):66-74.
[21] 李卫红,刘建宏,李通国,等.甘肃夏河—合作金富集区资源潜力分析:以金、银、锑地球化学块体为例[J].西北地质,2015,48(2):121-127.
LI Wei-hong,LIU Jian-hong,LI Tong-guo,et al.Analysis on Resource Potential of Xiahe-Hezuo Au Enrichment Area,Gansu:Taking Geochemical Blocks of Au,Ag and Sb as an Example[J].Northwestern Geology,2015,48(2):121-127.
[22] 殷鸿福.秦岭及邻区三叠系[M].武汉:中国地质大学出版社,1992.
YIN Hong-fu.The Triassic System in the Qinling Mountians and Adjacent Areas[M].Wuhan:China Univer-sity of Geosciences Press,1992.
[23] 赖旭龙,殷鸿福,杨逢清.秦岭三叠纪古海洋再造[J].地球科学,1995,20(6):648-656.
LAI Xu-long,YIN Hong-fu,YANG Feng-qing.Reconstruction of the Qingling Triassic Paleo-ocean[J].Earth Science,1995,20(6):648-656.
[24] 胡圣虹,胡兆初,刘勇胜,等.单个流体包裹体元素化学组成分析新技术:激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)[J].地学前缘,2001,8(4):434-440.
HU Sheng-hong,HU Zhao-chu,LIU Yong-sheng,et al.New Techniques of Major and Minor Elemental Analysis in Individual Fluid Inclusion:Laser Ablation Inductively Coupled Plasma Mass Spectrometry(LA-ICP-MS)[J].Earth Science Frontiers,2001,8(4):434-440.
[25] 张乐骏,周涛发.矿物原位LA-ICP-MS微量元素分析及其在矿床成因和预测研究中的应用进展[J].岩石学报,2017,33(11):3437-3452.
ZHANG Le-jun,ZHOU Tao-fa.Minerals In-situ LA-ICP-MS Trace Elements Study and the Applications in Ore Deposit Genesis and Exploration[J].Acta Pe-trologica Sinica,2017,33(11):3437-3452.
[26] 玉永珊.稀土元素分析测试方法在地质学上的应用[J].世界有色金属,2022,47(15):166-168.
YU Yong-shan.Application of Rare Earth Element Analysis and Testing Method in Geology[J].World Nonferrous Metals,2022,47(15):166-168.
[27] THOMPSON J M,MEFFRE S,DANYUSHEVSKY L.Impact of Air,Laser Pulse Width and Fluence on U-Pb Dating of Zircons by LA-ICP-MS[J].Journal of Analytical Atomic Spectrometry,2018,33(2):221-230.
[28] PATON C,WOODHEAD J D,HELLSTROM J C,et al.Improved Laser Ablation U-Pb Zircon Geochronology Through Robust Downhole Fractionation Correction[J].Geochemistry,Geophysics,Geosystems,2010,11(3):2009GC002618.
[29] 温子豪,李胜荣,袁茂文,等.小秦岭华山和文峪岩体成金潜力异同分析:来自锆石群形态标型的证据[J].地球科学与环境学报,2018,40(5):535-545.
WEN Zi-hao,LI Sheng-rong,YUAN Mao-wen,et al.Analysis of Similarities and Differences of Gold Potential Between Huashan and Wenyu Plutons in Xiaoqinling,China:Evidence from Morphological Characteristics of Zircons[J].Journal of Earth Sciences and Environment,2018,40(5):535-545.
[30] 雷玮琰.不同成因锆石的微量元素特征研究:以缅甸硬玉岩、山西金红石矿等中锆石为例[D].北京:中国地质大学,2013.
LEI Wei-yan.Trace Element Composition of Zircon from Myanmar Jadeitite,the Daixian Rutile Deposit and the Huangbaikeng Rhyolite Porphyry[D].Beijing:China University of Geosciences,2013.
[31] 隋吉祥.西秦岭夏河—合作地区与还原性侵入岩有关的金成矿作用[D].武汉:中国地质大学,2016.
SUI Ji-xiang.Gold Mineralization Associated with Reductive Intrusive Rocks in the Xiahe-Hezuo Region of the West Qinling Mountains[D].Wuhuan:China University of Geosciences,2016.
[32] HIBBARD M J.Textural Anatomy of Twelve Magma-mixed Granitic Systems[M]∥DIDIER J,BARBARIN B.Enclaves and Granite Petrology.Amesterdam:Else-vier,1991:431-444.
[33] 张 旗,潘国强,李承东,等.花岗岩混合问题:与玄武岩对比的启示——关于花岗岩研究的思考之一[J].岩石学报,2007,23(5):1141-1152.
ZHANG Qi,PAN Guo-qiang,LI Cheng-dong,et al.Granitic Magma Mixing Versus Basaltic Magma Mixing:New Viewpoints on Granitic Magma Mixing Pro-cess—Some Crucial Questions on Granite Study(1)[J].Acta Petrologica Sinica,2007,23(5):1141-1152.
[34] 王德滋,谢 磊.岩浆混合作用:来自岩石包体的证据[J].高校地质学报,2008,14(1):16-21.
WANG De-zi,XIE Lei.Magma Mingling:Evidence from Enclaves[J].Geological Journal of China Universities,2008,14(1):16-21.
[35] 关义立,袁 超,龙晓平,等.华南地块东部早古生代的陆内造山作用:来自I型花岗岩的启示[J].大地构造与成矿学,2013,37(4):698-720.
GUAN Yi-li,YUAN Chao,LONG Xiao-ping,et al.Early Paleozoic Intracontinental Orogeny of the Eastern South China Block:Evidence from I-type Granitic Plutons in the SE Yangtze Block[J].Geotectonica et Metallogenia,2013,37(4):698-720.
[36] 关义立,袁 超,龙晓平,等.华南早古生代花岗岩中暗色包体的成因:岩石学、地球化学和锆石年代学证据[J].大地构造与成矿学,2016,40(1):109-124.
GUAN Yi-li,YUAN Chao,LONG Xiao-ping,et al.Genesis of Mafic Enclaves from Early Paleozoic Gra-nites in the South China Block:Evidence from Petro-logy,Geochemistry and Zircon U-Pb Geochronology[J].Geotectonica et Metallogenia,2016,40(1):109-124.
[37] 曹 烨,李胜荣,李真真,等.太行山北段石湖金矿区中生代岩浆岩中单颗粒锆石的稀土元素特征及启示[J].中国稀土学报,2009,27(4):564-573.
CAO Ye,LI Sheng-rong,LI Zhen-zhen,et al.Characteristics of Rare Earth Elements of Zircon from Mesozoic Magmatic Rocks in Shihu Gold District,North Taihang Mountain,North China[J].Journal of the Chinese Rare Earth Society,2009,27(4):564-573.
[38] SUN S S,MCDONOUGH W F.Chemical and Isoto-pic Systematics of Oceanic Basalts:Implications for Mantle Composition and Processes[J].Geological Society,London,Special Publications,1989,42:313-345.
[39] 陈明辉,郭素雄,徐军伟,等.德乌鲁岩体内外接触带金多金属成矿区成岩成矿地质地球化学特征及成因探讨[J].矿产与地质,2016,30(4):517-530.
CHEN Ming-hui,GUO Su-xiong,XU Jun-wei,et al.Diagenetic,Metallogenic,Geological and Geochemical Characteristics of Gold Polymetallic Metallogenic Pro-vince Inside Inner and Outer Contact Zone of Dewulu Rock Mass[J].Mineral Resources and Geology,2016,30(4):517-530.
[40] HANCHAR J M,VAN WESTRENEN W.Rare Ear-th Element Behavior in Zircon-melt Systems[J].Elements,2007,3(1):37-42.
[41] 雷传扬,唐菊兴,李 威,等.班公湖—怒江缝合带西段阿翁错复式岩体的岩浆混合成因:地球化学、年代学和暗色微粒包体证据[J].岩石学报,2019,35(3):665-686.
LEI Chuan-yang,TANG Ju-xing,LI Wei,et al.Genesis of Magma Mixing and Mingling of the Awengcuo Composite Plutons in Western Segment of Bangongco-Nujiang Suture Zone:Evidence from Geochemistry,Geochronology and Mafic Microgranular Enclaves(MMEs)[J].Acta Petrologica Sinica,2019,35(3):665-686.
[42] BAKER D R.Tracer Versus Trace Element Diffusion:Diffusional Decoupling of Sr Concentration from Sr Isotope Composition[J].Geochimica et Cosmochimica Acta,1989,53(11):3015-3023.
[43] ALLEN C M.Local Equilibrium of Mafic Enclaves and Granitoids of the Turtle Pluton,Southeast California:Mineral,Chemical,and Isotopic Evidence[J].American Mineralogist,1991,76:574-588.
[44] HOLDEN P,HALLIDAY A N,STEPHENS W E,et al.Chemical and Isotopic Evidence for Major Mass Transfer Between Mafic Enclaves and Felsic Magma[J].Chemical Geology,1991,92(1/2/3):135-152.
[45] LESHER C E.Kinetics of Sr and Nd Exchange in Si-licate Liquids:Theory,Experiments,and Applications to Uphill Diffusion,Isotopic Equilibration,and Irreversible Mixing of Magmas[J].Journal of Geophysical Research:Solid Earth,1994,99(B5):9585-9604.
[46] 陈 伟,宋 杨,刘洪章,等.同源岩浆不同期次之间混合产生的暗色包体:以北拉萨地块中部晚白垩世桑心日岩体为例[J].岩石学报,2019,35(7):2143-2157.
CHEN Wei,SONG Yang,LIU Hong-zhang,et al.MMEs Formed by Magma Mixing of Different Episodes of the Same Sourced Magma:A Case Study of the Late Cretaceous Sangxinri Pluton in the Middle Part of the Northern Lhasa Block[J].Acta Petrologica Sinica,2019,35(7):2143-2157.
[47] 张泽斌,唐菊兴,唐 攀,等.西藏甲玛铜多金属矿床暗色包体岩石成因:对岩浆混合和成矿的启示[J].岩石学报,2019,35(3):934-952.
ZHANG Ze-bin,TANG Ju-xing,TANG Pan,et al.The Origin of the Mafic Microgranular Enclaves from Jiama Porphyry Cu Polymetallic Deposit,Tibet:Implications for Magma Mixing/Mingling and Mineralization[J].Acta Petrologica Sinica,2019,35(3):934-952.
[48] 李康宁,贾儒雅,李鸿睿,等.西秦岭早子沟金矿黑云母成分特征及成岩成矿指示意义[J].岩石矿物学杂志,2022,41(5):865-879.
LI Kang-ning,JIA Ru-ya,LI Hong-rui,et al.Composition Characteristics of Biotite and Its Implications for Diagenesis and Mineralization in Zaozigou Gold Deposit,Western Qinling[J].Acta Petrologica et Minera-logica,2022,41(5):865-879.
[49] 李康宁,张江苏,徐 进,等.西秦岭甘南加甘滩金矿床流体包裹体及氢-氧-硫-铅同位素特征[J].地质通报,2023,42(6):941-952.
LI Kang-ning,ZHANG Jiang-su,XU Jin,et al.Cha-racteristics of Fluid Inclusions and H-O-S-Pb Isotopic from the Jiagantan Gold Deposit,Gannan,West Qinling[J].Geological Bulletin of China,2023,42(6):941-952.
[50] SUI J X,LI J W,WEN G,et al.The Dewulu Reduced Au-Cu Skarn Deposit in the Xiahe-Hezuo District,West Qinling Orogen,China:Implications for an Intrusion-related Gold System[J].Ore Geology Revi-ews,2017,80:1230-1244.
[51] JIN X Y,LI J W,HOFSTRA A H,et al.Magmatic-Hydrothermal Origin of the Early Triassic Laodou Lode Gold Deposit in the Xiahe-Hezuo District,West Qinling Orogen,China:Implications for Gold Metallogeny[J].Mineralium Deposita,2017,52(6):883-902.
[52] WANG R,RICHARDS J P,HOU Z Q,et al.Increa-sed Magmatic Water Content:The Key to Oligo-Miocene Porphyry Cu-Mo±Au Formation in the Eastern Gangdese Belt,Tibet[J].Economic Geology,2014,109(5):1315-1339.
[53] 鲍新尚,和文言,高 雪.滇西北衙金矿床富水岩浆对成矿的制约[J].岩石学报,2017,33(7):2175-2188.
BAO Xin-shang,HE Wen-yan,GAO Xue.The Beiya Gold Deposit:Constraint from Water-rich Magmas to Mineralization[J].Acta Petrologica Sinica,2017,33(7):2175-2188.
[54] YANG K H,SCOTT S D.Magmatic Degassing of Vo-latiles and Ore Metals into a Hydrothermal System on the Modern Sea Floor of the Eastern Manus Back-arc Basin,Western Pacific[J].Economic Geology,2002,97(5):1079-1100.
[55] SUN W D,ARCULUS R J,KAMENETSKY V S,et al.Release of Gold Bearing Fluids in Convergent Margin Magmas Prompted by Magnetite Crystallization[J].Nature,2004,431:975-978.
[56] 秦克章,张连昌,丁奎首,等.东天山三岔口铜矿床类型、赋矿岩石成因与矿床矿物学特征[J].岩石学报,2009,25(4):845-861.
QIN Ke-zhang,ZHANG Lian-chang,DING Kui-shou,et al.Mineralization Type,Petrogenesis of Ore-bearing Intrusions and Mineralogical Characteristics of Sanchakou Copper Deposits in Eastern Tianshan[J].Acta Petrologica Sinica,2009,25(4):845-861.
[57] 张 琪,殷先明,殷 勇,等.西秦岭与埃达克岩和喜马拉雅型花岗岩有关的金铜成矿及找矿问题[J].岩石学报,2009,25(12):3103-3122.
ZHANG Qi,YIN Xian-ming,YIN Yong,et al.Issues on Metallogenesis and Prospecting of Gold and Copper Deposits Related to Adakite and Himalayan Type Granite in West Qinling[J].Acta Petrologica Sinica,2009,25(12):3103-3122.
[58] BOTCHARNIKOV R E,LINNEN R L,WILKE M,et al.High Gold Concentrations in Sulphide-bearing Magma Under Oxidizing Conditions[J].Nature Geoscience,2011,4:112-115.
[59] BALLARD J R,PALIN J M,CAMPBELL I H.Relative Oxidation States of Magmas Inferred from Ce(Ⅳ)/Ce(Ⅲ)in Zircon:Application to Porphyry Copper Deposits of Northern Chile[J].Contributions to Mineralogy and Petrology,2002,144(3):347-364.
[60] TRAIL D,WATSON E B,TAILBY N D.Ce and Eu Anomalies in Zircon as Proxies for the Oxidation Sta-te of Magmas[J].Geochimica et Cosmochimica Acta,2012,97:70-87.
[61] ZHANG C C,SUN W D,WANG J T,et al.Oxygen Fugacity and Porphyry Mineralization:A Zircon Perspective of Dexing Porphyry Cu Deposit,China[J].Geochimica et Cosmochimica Acta,2017,206:343-363.
[62] LEE R G,DILLES J H,TOSDAL R M,et al.Magmatic Evolution of Granodiorite Intrusions at the El Salvador Porphyry Copper Deposit,Chile,Based on Trace Element Composition and U/Pb Age of Zircons[J].Economic Geology,2017,112(2):245-273.
[63] LOADER M A,WILKINSON J J,ARMSTRONG R N.The Effect of Titanite Crystallisation on Eu and Ce Anomalies in Zircon and Its Implications for the Assessment of Porphyry Cu Deposit Fertility[J].Earth and Planetary Science Letters,2017,472:107-119.
[64] 韦 萍,莫宣学,喻学惠,等.西秦岭夏河花岗岩的地球化学、年代学及地质意义[J].岩石学报,2013,29(11):3981-3992.
WEI Ping,MO Xuan-xue,YU Xue-hui,et al.Geoche-mistry,Chronology and Geological Significance of the Granitoids in Xiahe,West Qinling[J].Acta Petrologica Sinica,2013,29(11):3981-3992.
[65] 徐学义,陈隽璐,高 婷,等.西秦岭北缘花岗质岩浆作用及构造演化[J].岩石学报,2014,30(2):371-389.
XU Xue-yi,CHEN Jun-lu,GAO Ting,et al.Grani-toid Magmatism and Tectonic Evolution in Northern Edge of the Western Qinling Terrane[J].Acta Petrologica Sinica,2014,30(2):371-389.
[66] 李占轲,胡 佳,张 君,等.秦岭造山带铅锌矿床中稀散金属分布规律与资源评价[J].地球科学,2025,DOI:10.3799/dqkx.2024.157.
LI Zhan-ke,HU Jia,ZHANG Jun,et al.Distribution and Resource of Dispersed Metals in Pb-Zn Deposits of the Qinling Orogenic Belt[J].Earth Science,2025,DOI:10.3799/dqkx.2024.157.
[67] 陈衍景.秦岭印支期构造背景、岩浆活动及成矿作用[J].中国地质,2010,37(4):854-865.
CHEN Yan-jing.Indosinian Tectonic Setting,Magmatism and Metallogenesis in Qinling Orogen,Central China[J].Geology in China,2010,37(4):854-865.
[68] 陈国超,裴先治,李瑞保,等.东昆仑东段香加南山花岗岩基的岩浆混合成因:来自镁铁质微粒包体的证据[J].地学前缘,2016,23(4):226-240.
CHEN Guo-chao,PEI Xian-zhi,LI Rui-bao,et al.Ge-nesis of Magma Mixing and Mingling of Xiangjianan-shan Granite Batholith in the Eastern Section of East Kunlun Orogen:Evidence from Mafic Microgranular Enclaves(MMEs)[J].Earth Science Frontiers,2016,23(4):226-240.
[69] 苟正彬,汪雄武,彭慧娟,等.西藏甲玛铜多金属矿床岩浆混合作用及对成矿的贡献[J].中国地质,2012,39(1):156-169.
GOU Zheng-bin,WANG Xiong-wu,PENG Hui-juan,et al.The Role of Magma Mingling in Mineralization of the Jiama Copper Polymetallic Deposit in Tibet[J].Geology in China,2012,39(1):156-169.
[70] 王志强,陈 斌,马星华.广西陆川—博白成矿带多期次岩浆活动与钨钼成矿作用[J].地质学报,2017,91(2):421-439.
WANG Zhi-qiang,CHEN Bin,MA Xing-hua.Multiple Magmatism in the Luchuan-Bobai Metallogenic Belt of Guangxi and Its Relationship with W-Mo Mi-neralization[J].Acta Geologica Sinica,2017,91(2):421-439.

Memo

Memo:
-
Last Update: 2025-03-20