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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第46卷

期数:

2024年第06期

页码:

775-789

栏目:

沉积地质与油气勘探

出版日期:

2024-12-15

文章信息/Info

Title:

Geochemical Characteristics of Light Hydrocarbon of Shale Oil in Upper Submember of the Fourth Member of Shahejie Formation, Dongying Sag, China

文章编号:

1672-6561(2024)06-0775-15

作者:

吴 达¹; 2; 谢小敏¹; 2*; 黄 代³; 罗翠娟⁴; 张金晴⁵; 康淑娟⁵; 6

(1. 长江大学 油气地球化学与环境湖北省重点实验室,湖北 武汉 430100; 2. 长江大学 资源与环境学院,湖北 武汉 430100; 3. 中石化经纬有限公司胜利地质录井公司,山东 东营 257000; 4. 苏州冠德能源科技有限公司,江苏 苏州 215149; 5. 中国科学院地质与地球物理研究所,北京 100029; 6. 中国科学院地球与行星物理重点实验室,北京 100029)

Author(s):

WU Da¹; 2;  XIE Xiao-min¹; 2*;  HUANG Dai³;  LUO Cui-juan⁴;  ZHANG Jin-qing⁵;  KANG Shu-juan⁵; 6

(1. Hubei Key Laboratory of Petroleum Geochemistry and Environment, Yangtze University, Wuhan 430100, Hubei, China; 2. College of Resources and Environment, Yangtze University, Wuhan 430100, Hubei, China; 3. Shengli Geological Mud Logging Company, SINOPEC Jingwei Co., Ltd., Dongying 257000, Shandong, China; 4. Suzhou Grand Energy Technology Ltd., Suzhou 215149, Jiangsu, China; 5. Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China; 6. Key Laboratory of Earth and Planetary Physics, Chinese Academy of Sciences, Beijing 100029, China)

关键词:

页岩油;  沙河街组四段;  轻烃;  地球化学;  母质类型;  成熟度;  次生作用;  东营凹陷

Keywords:

shale oil;  the fourth member of Shahejie Formation;  light hydrocarbon;  geochemistry;  parent material type;  maturity;  alteration;  Dongying sag

分类号:

P618.13

DOI:

10.19814/j.jese.2024.04041

文献标志码:

A

摘要:

页岩油是常规油气重要的战略接替资源。借助轻烃进行地球化学特征研究,探讨轻烃在页岩油研究中的应用。通过全油色谱实验,对东营凹陷牛庄洼陷沙四上亚段纯上3层组和博兴洼陷沙四上亚段纯上2层组、3层组3个页岩油样品轻烃进行精细研究。结果表明:①轻烃蚀变参数显示3个层段原油未遭受明显的次生蚀变作用影响,轻烃参数反映的地球化学信息是有效的; ②轻烃参数甲基环己烷指数指示页岩油母质类型为湖相腐泥型,但轻烃C₆和C₇组成显示牛庄洼陷和博兴洼陷页岩油母质来源存在差异; ③由于研究区镜质组含量少,所以根据轻烃经验公式计算得出等效镜质体反射率为0.71%～0.90%,表明3个层段原油属于中等成熟原油,庚烷轻烃参数指示博兴洼陷成熟度略高。

Abstract:

Shale oil is an important strategic replacement resource for conventional oil and gas. In recent years, many shale oil wells in Boxing and Niuzhuang depressions of Dongying sag have made breakthroughs in the upper submember of the fourth member of Shahejie Formation. The geochemical characteristics of light hydrocarbons were studied, and the application of light hydrocarbons in the study of shale oil was explored. The light hydrocarbons in three shale oil samples of the upper submember 3 of the fourth member of Shahejie Formation in Niuzhuang depression and the upper submembers 3 and 2 of the fourth member of Shahejie Formation in Boxing depression were studied by whole petroleum chromatography. The results show that ① the light hydrocarbon alteration parameters show that the three submembers of crude oil is not affected by obvious secondary alteration, and the geochemical information of the light parameter reaction is effective; ②the light hydrocarbon parameter(MCH-Ⅰ)indicates that the parent material type of shale oil is lacustrine sapropelic type, but the compositions of light hydrocarbon C₆ and C₇ indicate that the parent material source of shale oil in Niuzhuang and Boxing depressions is different; ③ due to the low content of vitrinite in the study area, it is difficult to determine the reflectance of vitrinite; the reflectance of equivalent vitrinite is between 0.71% and 0.90% according to the empirical formula of light hydrocarbon, which indicates that the crude oil of the three submembers belongs to the medium mature crude oil, and the parameters of heptane light hydrocarbon indicate that the maturity of Boxing depression is slightly higher.

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收稿日期:2024-04-30; 修回日期:2024-07-18
基金项目:国家自然科学基金项目(42173055); 湖北省教育厅优秀青年创新团队项目(T2022008)
*通信作者:谢小敏(1984-),女,布依族,贵州开阳人,教授,博士研究生导师,理学博士,E-mail:xiaominxie2019@sina.com。

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