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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第47卷

期数:

2025年第05期

页码:

871-900

栏目:

基础地质与矿床地质

出版日期:

2025-10-01

文章信息/Info

Title:

Middle-Late Jurassic Granites in Nanling Region, South China: Insights from Bulk-rock Nd and Zircon Hf Isotope Mapping on the Spatial Distribution of “Tungsten in the East, Tin in the West”

文章编号:

1672-6561(2025)05-0871-30

作者:

郑义¹; 郭春丽¹; 2*; 陈振宇¹; 张斌武¹; 赵迁迁¹; 闫金禹¹; 许箭琪¹; 3

(1. 中国地质科学院矿产资源研究所 自然资源部成矿作用与资源评价重点实验室,北京 100037; 2. 中国地质科学院 深地探测与矿产勘查全国重点实验室,北京 100094; 3. 合肥工业大学 资源与环境工程学院,安徽 合肥 230009)

Author(s):

ZHENG Yi¹;  GUO Chun-li¹; 2*;  CHEN Zhen-yu¹;  ZHANG Bin-wu¹;  ZHAO Qian-qian¹;  YAN Jin-yu¹;  XU Jian-qi¹; 3

(1. MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China; 2. State Key Laboratory of Deep Earth and Mineral Exploration, Chinese Academy of Geological Sciences, Beijing 100094, China; 3. School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China)

关键词:

稀有金属;  花岗岩;  钨矿;  锡矿;  全岩Nd同位素;  锆石Hf同位素;  中—晚侏罗世;  南岭地区

Keywords:

rare metal;  granite;  tungsten deposit;  tin deposit;  whole-rock Nd isotope;  zircon Hf isotope;  Middle-Late Jurassic;  Nanling region

分类号:

P618.44; P618.67

DOI:

10.19814/j.jese.2024.08026

文献标志码:

A

摘要:

南岭地区发育大规模与花岗岩有关的中—晚侏罗世岩浆-热液型钨锡多金属矿床,并在空间上呈现出“东钨西锡”的分布规律。以郴州—临武断裂为界,多数钨矿床分布于南岭地区东段的赣南—粤北地区,而锡矿床则集中在南岭地区西段的湘南—桂北地区。为了更好地展示南岭地区钨锡矿床空间分布规律与花岗岩岩浆源区物质组成之间的关系,探究造成成钨花岗岩、成锡花岗岩成矿差异性的原因,全面搜集了中—晚侏罗世与钨锡成矿相关的61个花岗岩体全岩Nd和锆石Hf同位素数据,通过ArcGIS10.2软件绘制了Nd-Hf同位素和地壳模式年龄等值线图。结果表明:南岭地区花岗岩的全岩ε_Nd(t)值为-15.9～-0.8,锆石ε_Hf(t)值为-17.7～1.7; 总体来看,南岭地区东段花岗岩显示相对富集的Nd-Hf同位素特征,其ε_Nd(t)值和ε_Hf(t)值集中分布于-15.9～-7.9和-17.7～-4.1,暗示其源区以古老地壳的部分熔融为主; 而南岭地区西段花岗岩具有相对亏损的ε_Nd(t)值(-9.3～-1.7)和ε_Hf(t)值(-6.4～1.7),表明其岩浆源区具有更高的幔源物质组分。同时,壳幔二端元混合体系计算及He-Ar同位素投图结果也显示,南岭地区西段成锡花岗岩幔源组分显著高于东段成钨花岗岩。结合前人研究成果发现,南岭地区钨锡矿床空间分布的差异性可能与地幔参与程度有关。

Abstract:

The Nanling region has witnessed the development of large-scale Middle-Late Jurassic magmatic-hydrothermal tungsten-tin polymetallic deposits associated with granite, and spatially presents a distribution pattern of “tungsten in the east, tin in the west”. Taking Chenzhou-Linwu fault as the boundary, the majority of tungsten deposits are distributed in the eastern part of Nanling region, namely the southern Jiangxi-northern Guangdong, while tin deposits are concentrated in the western part of Nanling region, namely the southern Hunan-northern Guangxi. To better demonstrate the relationship between the spatial distribution of tungsten and tin deposits in Nanling region and the material composition of the granite magma source, and to explore the reasons for the metallogenic differences of tungsten- and tin-bearing granites, the whole-rock Nd and zircon Hf isotope data of 61 granite bodies related to tungsten and tin mineralization in Middle-Late Jurassic were comprehensively collected, and the contour maps of Nd-Hf isotope and crustal model ages were plotted through software ArcGIS10.2. The results show that the bulk-rock ε_Nd(t)value of granites in Nanling region is -15.9--0.8, and zircon ε_Hf(t)value is -17.7-1.7; overall, the granites in the eastern part of Nanling region exhibit relatively enriched Nd-Hf isotope characteristics, their ε_Nd(t)and ε_Hf(t)values are concentrated in the ranges of -15.9--7.9 and -17.7--4.1, respectively, suggesting that they originate from the partial melting of the ancient crust; while the granites in the western part of Nanling region have relatively high ε_Nd(t)values(-9.3--1.7)and ε_Hf(t)values(-6.4-1.7), respectively, indicating that their magma source have more mantle-derived components. Additionally, quantitative modeling of the crust-mantle binary mixing system, complemented by He-Ar isotopic analyses, reveals that the mantle-derived contribution in tin-bearing granites from the western part significantly exceeds that in tungsten-bearing granites from the eastern part. Integrating these findings with previous research, the distinct spatial distribution of tungsten-tin deposits in Nanling region may be related to the different contribution degree of mantle-derived components.

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备注/Memo

备注/Memo:

收稿日期:2024-08-26; 修回日期:2025-02-21
基金项目:国家自然科学基金项目(92162210,42172096); 中国地质调查局地质调查项目(DD20221695)
*通信作者:郭春丽(1978-),女,河北石家庄人,研究员,博士研究生导师,工学博士,E-mail:gchunli@126.com。

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