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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第44卷

期数:

2022年第03期

页码:

431-447

栏目:

基础地质与矿产地质

出版日期:

2022-05-15

文章信息/Info

Title:

Zircon U-Pb Geochronology, Geochemical Characteristics and Geological Significance of Ore-bearing Volcanics from Zhihe Cyprus-type Cu Deposit in the Northern Qilian Orogeny, China

文章编号:

1672-6561(2022)03-0431-17

作者:

赵辛敏¹; 2; 郭周平¹; 2; 白 赟³; 张江伟¹; 2; 燕洲泉¹; 2

(1. 中国地质调查局西安地质调查中心,陕西 西安 710054; 2. 自然资源部岩浆作用成矿与找矿重点实验室,陕西 西安 710054; 3. 核工业西藏地质调查院,四川 成都 610052)

Author(s):

ZHAO Xin-min¹; 2;  GUO Zhou-ping¹; 2;  BAI Yun³;  ZHANG Jiang-wei¹; 2;  YAN Zhou-quan¹; 2

(1. Xi'an Center of Geological Survey, China Geological Survey, Xi'an 710054, Shaanxi, China; 2. Key Laboratory for the Study of Focused Magmatism and Giant Ore Deposits of Ministry of Natural Resources, Xi'an 710054, Shaanxi, China; 3. Tibet Institute of Geological Survey of Nuclear Industry, Chengdu 610052, Sichuan, China)

关键词:

细碧岩;  地球化学;  锆石U-Pb年龄;  岩石成因;  塞浦路斯型;  铜矿;  北祁连

Keywords:

spilite;  geochemistry;  zircon U-Pb age;  petrogenesis;  cyprus-type;  Cu deposit;  northern Qilian

分类号:

P595; P611

DOI:

10.19814/j.jese.2021.12028

文献标志码:

A

摘要:

直河铜矿位于北祁连构造带中东段冷龙岭火山岩带内,铜矿化主要赋存在基性火山岩(细碧岩)中,并有喷流岩(碧玉岩)相伴生,矿石类型主要为块状铜矿石,属于塞浦路斯型块状硫化物矿床。LA-ICP-MS锆石U-Pb定年获得赋矿细碧岩年龄为(457.1±2.8)Ma,表明成岩时代为晚奥陶世。细碧岩TiO₂含量(质量分数,下同)为1.12%～1.37%,介于岛弧拉斑玄武岩和洋脊玄武岩之间,强烈富集大离子亲石元素,亏损Nb、Ta等高场强元素,类似岛弧火山岩特征,而稀土元素配分模式呈平坦型轻稀土元素亏损特征,与洋脊玄武岩(N-MORB)类似,其地球化学特征介于岛弧和洋脊玄武岩之间,显示其产出于弧后盆地环境。直河铜矿含矿火山岩钠化较强(Na₂O含量大于4%),说明水-岩交换反应强烈,循环对流热液体系可从海底火山岩中溶滤出的金属成矿物质较多,显示出较好的成矿潜力。直河塞浦路斯型铜矿与同处于冷龙岭火山岩带的银灿黑矿型铜锌铅矿、浪力克次火山岩型铜矿、毛藏寺斑岩型铜钼矿共同构成了奥陶纪弧-盆成矿系统。

Abstract:

Located in Lenglongling volcanic belt, the middle-east part of the northern Qilian orogeny, Zhihe Cu deposit is massive copper mineralization occurring in basic volcanic rocks(spilite), and accompanied by exhalation rocks(jasper rocks), which belongs to Cyprus-type massive sulfide deposit. Zircon LA-ICP-MS dating yields concordant ages of(457.1±2.8)Ma of the ore-bearing volcanic rocks, indicating Zhihe Cu deposit formed in Late Ordovician. Geochemical data show that the spilite belongs to the calc-alkaline series and has the content of TiO₂(1.12%-1.37%)between island arc tholeiite and ridge tholeiite, which are characterized by enrichment of LILEs, and depletion of HFSEs(such as Nb and Ta), similar to those by typical island-arc volcanic rocks; the spilite is characterized by depletion of LREE and flat distribution of chondrite-normalized REE pattern, which is similar to those of N-MORB. The basic volcanic rocks have both arc-like and MORB-like geochemical features, which reflect a tectonic setting of back arc basin. The ore-bearing volcanic rocks have a strong sodiumification(content of Na₂O is more than 4%). The strong water-rock exchange reaction in Zhihe Cu deposit lead the metal amount derived from volcanic rocks, which had suffered recycled hydrothermal fluid metasomatism and the leaching is more, indicating that it may has a certain mineralization potential. Zhihe Cyprus-type Cu deposit, Yincan Kuroko-type Cu-Zn-Pb deposit, Langlike subvolcanic-type Cu deposit and Maozangsi porphyry Cu-Mo deposit, which are also located in Lenglongling volcanic belt, constitute the Ordovician arc-basin metallogenic system.

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备注/Memo

备注/Memo:

收稿日期:2021-12-15; 修回日期:2022-01-26
基金项目:国家重点研发计划项目(2019YFC0605201); 陕西省自然科学基础研究计划项目(2022JQ-268);
第二次青藏高原综合科学考察研究专题(2021QZKK0303); 中国地质调查局地质调查项目(DD20190143)
作者简介:赵辛敏(1988-),男,山西临汾人,中国地质调查局西安地质调查中心工程师,E-mail:835177076@qq.com。

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