|本期目录/Table of Contents|

[1]张维海,赵建社,孙庆津,等.砂岩型铀矿成矿过程中腐殖酸的化学作用[J].地球科学与环境学报,2006,28(04):38-42.
　ZHANG Wei-hai,ZAHO Jian-she,SUN Qing-jin,et al.Role of Humic Acid in Mineralization of Sandstone-Type Uranium Deposits[J].Journal of Earth Sciences and Environment,2006,28(04):38-42.
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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:
第28卷
期数:
2006年第04期
页码:
38-42
栏目:
出版日期:
2006-12-15

文章信息/Info

Title:
Role of Humic Acid in Mineralization of Sandstone-Type Uranium Deposits
作者:
张维海1; 赵建社1; 孙庆津1; 苗建宇2; 孙卫2; 薛春纪3
1.西北大学物理无机化学陕西省重点实验室,陕西西安710069; 2.西北大学地质学系,陕西西安710069;3.中国地质大学地球科学与资源学院,北京100083
Author(s):
ZHANG Wei-hai1; ZAHO Jian-she1; SUN Qing-jin1; MIAO Jian-yu2; SUN Wei2; XUE Chun-ji3
1. Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi’an 710069, Shaanxi, China; 2. Department of Geology, Northwest University, Xi’an 710069, Shaanxi, China; 3. School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
关键词:
腐殖酸; 铀矿; 模拟; 配位反应; 结构构型
Keywords:
humic acid;  uranium mineralization;  simulation;  coordination reaction;  structure
分类号:
O741+.2;P619.14
DOI:
-
文献标志码:
A
摘要:
研究表明,腐殖酸在铀成矿过程中的化学作用受多种因素制约,如pH值、温度和离子强度等。由于腐 殖酸和富啡酸结构中的一些单元与一些小分子的芳香有机酸相似,因此,利用小分子的芳香有机酸来代替腐殖 酸,研究不同条件下腐殖酸对铀成矿的影响,并获得了不同形式铀的配合物,证明了铀在含腐殖酸环境中的赋存 状态。
Abstract:
The role of the humic acid in the process of mineralization of sandstone-type uranium deposits is influ- enced by some factors like pH value, temperature and ionic strength. Because some structural units of humic acid and fulvic acid are similar to aromatic organic acid of small molecular weight, in order to study the influence of humic acid in the process of mineralization of sandstone-type uranium deposits, some uranium complexes is ob- tained the existing state of uranium in humic acid is testified by using aromatic organic acid to replace humic acid.

参考文献/References:

[1] 郭海花，常象春，张金 亮. 兰坪坳 陷上三 叠统原 油地球 化学 及有机成矿意义[J]. 长安 大学学 报 :地 球科 学版，2003，25 (4):1 5.
[2] 王 涛，刘淑文，隗 合明，等. 热 水沉积矿床研究的现状与趋 势[J]. 地球科学与环境学报，2004，26(4):6 10.
[3] T urner-Peterson C E，Fishm an N S，H at ch er P G，et al. Nature and Role of Organic Mat t er in S andst one Uranium Deposit s[M] . Berlin :S pringer Press，1993.
[4] Gi ze A. The Analysis of Organic Mat ter in Ore Deposit s [M] . Berlin :S pringer Press，1993.
[5] Jehlicka J，Rou zau d J N. Transmi ssion Elect ron Microscopy of Carbonaceaou s Mat t er in P recambrian S hungi te f rom Karelia[M] . Berlin :S pringer Press，1993.
[6] Landai s P, Du bes sy J，Poty B, et al. Th ree Examples Illust rating the Analysi s of Organic Mat ter As sociat ed wi th U ranium Ores[J] . O re Geochem，1990，16 :601 608.
[7] Landais P. Organic Geochemist ry of Sediment ary Uranium ore Deposi ts[J] . Ore Geol ogy Review s，1996，11 :33 51.
[8] Liu A，Gonzalez D. Modelin g Adsorpt ion of Copper (II), Cadmium (II) an d Lead (II) on Pu ried H umic Acid[J] . Langmui r, 2000，16 :3 902 3 909.
[9] Ping Zhou，H ui Yan，Baohu a Gu. C om pet it ive Complexation of Metal Ion s w ith Humi c Su bst ances [J] . Chemosphere , 2005，58 :1 327 1 337.
[10] Lubal P，Fet sch D, iroky’ D S，et al. Potent io-M et ric and Spect roscopi c Study of Uranyl Complexation w ith Humic Acid s[J] . Talant a, 2000，51 :977 991.
[11] Rabin ovi tch E，Belf ord R L. Spect roscopy an d Phot ochemi st ry of Urany l Compou nds[M] . New York :Pergam on Press， 1964.
[12] Choppin G R. Humi cs and Radionuclide Mig rat ion[J] . Radiochim Acta，1988，45 :23 28.
[13] Goncalves M L S，M ota A M A M. Compl exes of Vanadyl and Uranyl Ions wi th the Chelating Groups of Humi c Mat ter [J] . T alant a, 1987，34 :839 847.
[14] Tem pleton G D, Chasteen N D. Vanadium-Ful vic Acid Chemist ry :Conf ormati on al and Bindin g Studies by El ectron S pin Probe Tech niques[J] . Geochim Cosm ochim Acta，1980，44 : 741 752.
[15] Wi lson D E，Kin ney P. Eff ect s of Polymeric Charge Variati ons on the Prot on-metal Ion Equilib ri a of Humi c Materials [J] . Limnol Oceanog r, 1977，22 :281 289.
[16] Wood S A. The Role of H umic S ubst ances in the Transpo rt and Fixat ion of Metals of E conomic In teres t (Au，Pt，Pd， U，V) [J] . Ore Geology Review s，1996，11 :1 31.

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备注/Memo

备注/Memo:
[收稿日期]2006-02-23
[基金项目]国家重点基础研究发展计划项目(2003CB214600)
[作者简介]张维海(1980-),男,山东沂水人,硕士研究生,从事地球化学和金属有机化学研究。
更新日期/Last Update: 2006-12-20