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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第34卷

期数:

2012年第01期

页码:

66-71

栏目:

水资源与环境

出版日期:

2012-03-20

文章信息/Info

Title:

Investigation and research on volatile halogenated hydrocarbon contamination from groundwater in 69 cities of China

作者:

高存荣; 王俊桃

中国地质环境监测院,北京 100081

Author(s):

GAO Cun-rong;  WANG Jun-tao

China Institute of Geo-environmental Monitoring, Beijing 100081, China

关键词:

地下水;  挥发性卤代烃;  污染;  检测;  城市;  氯仿;  检出率;  超标率

Keywords:

groundwater;  volatile halogenated hydrocarbon;  contamination;  detection;  city;  chloroform;  detection ratio;  over standard rate

分类号:

P641.3; X523

DOI:

-

文献标志码:

A

摘要:

为了初步掌握中国主要城市地下水挥发性卤代烃污染状况和特征,在中国69个城市开展了地下水挥发性卤代烃污染检测与特征研究,采集地下水样品791组,采样井均为工农业生产和生活饮用水水井; 依据US EPA 8260B检测方法,采用气相色谱/质谱联用分析仪器(P&T-GC/MS),分析和测试了氯仿、四氯化碳、1,1,1-三氯乙烷、三氯乙烯、四氯乙烯和二氯甲烷等15种挥发性卤代烃的质量浓度。结果表明:在791组地下水样品中,有406组样品至少有一种挥发性卤代烃组分被检出,检出率为51.33%; 各组分中,氯仿的检出率最高,为20.35%,其他组分的检出率为0.25%～5.06%; 氯乙烯在所有样品中均未检出; 有13组样品的单项组分超标,超标率为1.64%; 超标率由高到低分别为四氯化碳(0.76%)、氯仿(0.25%)、1,2-二氯乙烷(0.25%)、三氯乙烯(0.13%)、1,1,2-三氯乙烷(0.13%)、1,2-二氯丙烷(0.13%); 超标井均为非供水水源地水井。检测与研究结果表明:中国主要城市地下水挥发性卤代烃污染物检出率较高,检测的69个城市中71%的城市至少有一种挥发性卤代烃被检出,且潜水的检出率高于承压水,但总体超标率较低。

Abstract:

In order to understand the contamination situation and characteristics of volatile halogenated hydrocarbon(VHH)in groundwater of main cities, China, the investigation and research on VHH contamination from groundwater in 69 cities of China were carried out. 791 groundwater samples were collected from wells for industrial and agricultural production and wells for living and drink; mass concentrations of 15 kinds of VHHs, which were chloroform, carbon tetrachloride, 1,1,1-trichloroethane, trichloroethylene, tetracarp, dichloromethane and so on, were analyzed with the analytical apparatus combined gas chromatography and mass spectrometry(P&T-GC/MS)based on US EPA 8260B test method. The results showed that at least one kind of VHHs could be detected in 406 groundwater samples, and the detection ratio of the samples to the 791 groundwater samples was 51.33%; the detection ratio for chloroform was highest(20.35%)among the VHHs, and the ratios for other VHHs were 0.25%-5.06%; no chloroethylene was detected in all the samples; mass concentrations of single VHH of 13 groundwater samples exceeded the standard value, and the over standard rate was 1.64%; VHHs with the over standard rate ranked in descending order were carbon tetrachloride(0.76%), chloroform(0.25%), 1,2-dichloroethane(0.25%), trichloroethylene(0.13%), 1,1,2-trichloroethane(0.13%)and 1,2-dichloropropane(0.13%); mass concentrations of VHHs from the wells in drinking water source area were lower than that in other areas. In general, the detection ratios of VHHs contamination from groundwater in main cities of China were high, at least one kind of VHHs could be detected in 71% of the 69 cities, and the detection ratios in unconfined aquifer were higher than that in confined aquifer, but the over standard rates were low.

参考文献/References:

[1] ROOK J J.Formation of haloforms during chlorination of na-tural waters[J].Water Treatment and Examination,1974,23:234-240.
[2] BELLAR T A,LICHTENBERG J J,KROFLER R C.The occur-rence of organohalides in chlorinated drinking water[J].Journal AWWA,1974,66(12):703-706.
[3] BIANCHI A P,VANMY M S,PHILIPS J.Analysis of volatile organic compounds in estuarine sediments using dynamic headspace and gas chromatography:mass spectrometry[J].Journal of Chromatography A,1991,542:413-450.
[4] 李 杨.临沂市饮用水挥发性卤代烃污染的研究[J].中国热带医学,2008,8(1):155-157. LI Yang.Study on the levels of volatile halogenated hydrocarbon in drinking water in Linyi City[J].China Tropical Medicine,2008,8(1):155-157.(in Chinese)
[5] 赵国栋.我国部分省市饮用水中挥发性卤代烃含量初步调查[J].环境化学,1986,5(3):84-86. ZHAO Guo-dong.Preliminary investigation on volatile halogenated hydrocarbon content in drinking water in some cities in China[J].Environmental Chemistry,1986,5(3):84-86.(in Chinese)
[6] 俞 飞,陈建平,武志林,等.某市自来水中挥发性卤代烃污染的研究[J].环境与健康杂志,1992,9(3):112-114. YU Fei,CHEN Jian-ping,WU Zhi-lin,et al.Research on vola-tile halogenated hydrocarbon contamination in tap water in some certain city[J].Journal of Environment and Health,1992,9(3):112-114.(in Chinese)
[7] 蔡宏道.水氯化消毒与致癌问题[J].国外医学参考资料:卫生学分册,1979,6(2):65-68. CAI Hong-dao.Water chlorine disinfection and carcinogenic problems[J].Overseas Medicine Reference:Hygiene Fascicule,1979,6(2):65-68.(in Chinese)
[8] 蒋守芳,郭 忠,段江平,等.唐山市生活饮用水挥发性卤代烃类含量调查[J].现代预防医学,2011,38(2):225-227. JIANG Shou-fang,GUO Zhong,DUAN Jiang-ping,et al.Investigation on the level of volatile halogenated hydrocarbons in drinking-water in Tangshan City[J].Modern Preventive Medicine,2011,38(2):225-227.(in Chinese)
[9] 邓延慧,李 娟.饮用水中卤代产物及前驱物的形成与控制[J].污染防治技术,2007,20(5):64-65,89. DENG Yan-hui,LI Juan.Study on the formation and control of halogenated hydrocarbon compounds and the precursors in drinking water[J].Pollution Control Technology,2007,20(5):64-65,89.(in Chinese)
[10] 路国慧,杨永亮,刘晓端,等.沈阳地区河水及沿岸地下水中卤代烃的污染特征[J].岩矿测试,2009,28(4):316-320. LU Guo-hui,YANG Yong-liang,LIU Xiao-duan,et al.Con-tamination characteristics of halohydrocarbons in surface water and ground water from Shenyang Area[J].Rock and Mineral Analysis,2009,28(4):316-320.(in Chinese)
[11] 魏科霞,尹起范.不同水体中挥发性卤代烃的对比[J].淮阴师范学院学报:自然科学版,2005,4(2):127-130. WEI Ke-xia,YIN Qi-fan.Comparison for volatile halohydrocarbons in different water[J].Journal of Huaiyin Teachers College:Natural Science Edition,2005,4(2):127-130.(in Chinese)
[12] 刘明礼.对饮用水中有机污染物的控制[J].油气田环境保护,1995,5(1):31-35. LIU Ming-li.Control of organic pollutants in drinking water[J].Environmental Protection of Oil and Gas Fields,1995,5(1):31-35.(in Chinese)
[13] PFAFFENBERGER C D,CANTOR K P,PEOPLES A J,et al.Environmental impact and health effects[C]∥Committee of the Third Conference on Water Chlorination.Proceedings of the Third Conference on Water Chlorination:Environmental Impact and Health Effects.Ann Arbor:Ann Arbor Science Publishers,1980:1059-1075.
[14] PFAFFENBERGER C D,PEOPLES A J.Long-term variation study of blood plasma levels of chloroform and related purgeable compounds[J].Journal of Chromatography A,1982,239:217-226.
[15] 丁锦春.水中挥发性卤代烃的危害性及其分析方法的研究现况[J].中国卫生检验杂志,1995,5(6):364-366. DING Jin-chun.Review on harmfulness of volatile halogenated hydrocarbon in water and the research methods[J].Chinese Journal of Health Laboratory Technology,1995,5(6):364-366.(in Chinese)
[16] SINGER P C,BARRY J J,PALEN G M et al.Trihalomethane formation in North Carolina drinking waters[J].Journal AWWA,1981,73(8):392-401.
[17] REUNANEN M, KRONELD R.Determination of volatile halocarbons in raw and drinking water,human serum,and urine by electron capture GC[J].Journal of Chromatographic Science,1982,20(10):449-454.
[18] HAJIMIRAGHA H,EWERS U,JANSEN-ROSSECK R,et al.Human exposure to volatile halogenated hydrocarbons from the general environment[J].International Archives of Occupational and Environmental Health,1986,58(2):141-150.
[19] Jolley R L.Water chlorination:environmental impact and health effects[C]∥Committee of the Third Conference on Water Chlorination.Proceedings of the Third Conference on Water Chlorination:Environmental Impact and Health Effects.Ann Arbor:Ann Arbor Science Publishers,1980:55-56.
[20] DD 2008-01,地下水污染地质调查评价规范[S]. DD 2008-01,standard of geological survey and assessment of groundwater contamination[S].(in Chinese)
[21] GB 5479—2006,生活饮用水卫生标准[S]. GB 5749—2006,standards for drinking water quality[S].(in Chinese)
[22] EPA 822-R04-005,2004 edition of the drinking water standards and health advisories[S].

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备注/Memo

备注/Memo:

收稿日期:2011-08-31
基金项目:财政部国家级地质环境监测与预报项目(1212140501001)
作者简介:高存荣(1960-),男,内蒙古呼和浩特人,教授级高级工程师,理学博士,从事水文地质、环境地质调查监测研究,E-mail:gaocr@mail.cigem.gov.cn。

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更新日期/Last Update: 2012-03-20