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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第42卷

期数:

2020年第02期

页码:

188-198

栏目:

基础地质与矿产地质

出版日期:

2020-03-15

文章信息/Info

Title:

He-Ar Isotope Geochemical Characteristics of Ore-forming Fluids for Panzijian Gold Deposit in Jiaodong Area of Shandong, China

文章编号:

1672-6561(2020)02-0188-11

作者:

毛光周¹; 2; 3; 何铁良¹; 2; 许庆林¹; 杨锋杰¹; 2; 曹明平¹; 安鹏瑞¹;  窦义鑫¹; 于晓卫²; 刘晓通⁴; 孟令强⁵; 宋立国¹

(1. 山东科技大学 地球科学与工程学院,山东 青岛 266590; 2. 山东省地质调查院,山东 济南 250014; 3. 山东省地质科学研究院 国土资源部金矿成矿过程与资源利用重点实验室/山东省金属矿产成矿地质过程与资源利用重点实验室,山东 济南 50013; 4. 荣成市人才创新发展中心,山东 荣成 264300;5. 永城煤电控股集团有限公司新桥煤矿,河南 永城 476600)

Author(s):

MAO Guang-zhou¹; 2; 3;  HE Tie-liang¹; 2;  XU Qing-lin¹;  YANG Feng-jie¹; 2;  CAO Ming-ping¹;  AN Peng-rui¹;  DOU Yi-xin¹;  YU Xiao-wei²;  LIU Xiao-tong⁴;  MENG Ling-qiang⁵;  SONG Li-guo¹

(1. College of Earth Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, Shandong, China; 2. Shandong Institute of Geological Survey, Jinan 250014, Shandong, China; 3. Key Laboratory of Gold Mineralization Processes and Resource Utilization Subordinated to Ministry of Land and Resources/Key Laboratory of Metallogenic Geological Process and Resources Utilization in Shandong Province, Shandong Institute of Geological Sciences, Jinan 250013, Shandong, China; 4. Talent Innovation and Development Center of Rongcheng, Rongcheng 264300, Shandong, China; 5. Xinqiao Coal Mine, Yongcheng Coal and Electricity Holding Group Co., Ltd., Yongcheng 476600, Henan, China)

关键词:

地球化学;  金矿;  He-Ar同位素;  成矿流体;  黄铁矿;  流体包裹体;  富集地幔;  山东

Keywords:

geochemistry;  gold deposit;  He-Ar isotope;  ore-forming fluid;  pyrite;  fluid inclusion;  enriched mantle;  Shandong

分类号:

P597; P611

DOI:

10.19814/j.jese.2019.10042

文献标志码:

A

摘要:

盘子涧金矿地处山东胶东地区蓬莱—栖霞金成矿带南部,是典型的石英脉型金矿,Au品位高,目前对该矿床成矿流体来源的研究尚不深入。在详细的矿相学观察及黄铁矿显微结构研究基础上,对盘子涧金矿主成矿阶段(石英-黄铁矿(绢云母)阶段和金-石英-多金属硫化物阶段)的载金黄铁矿进行了流体包裹体He-Ar同位素组成分析。结果表明:盘子涧金矿载金黄铁矿中流体包裹体的³He丰度为(3.49～8.50)×10^-14 cm³ STP·g^-1,⁴He丰度为(2.46～5.06)×10^-8 cm³ STP·g^-1,³He/⁴He值为0.8R_a～1.2R_a(R_a为大气³He/⁴He值,R_a=1.39×10^-6),成矿流体表现出以富集地幔为主导的壳幔混合特征; ⁴⁰Ar丰度为(1.02～2.65)×10^-7 cm³ STP·g^-1,⁴⁰Ar/³⁶Ar值为896.3～1 724.1,是大气饱和水⁴⁰Ar/³⁶Ar值的2～3倍,与中国东北部幔源岩样品⁴⁰Ar/³⁶Ar值相近,推测成矿流体主要来源于富集地幔,成矿流体中存在着一定量的地壳放射性成因⁴⁰Ar,表明地壳流体参与了成矿作用。综上所述,推断山东胶东地区盘子涧金矿成矿流体为以富集地幔流体为主导的壳幔混合流体。

Abstract:

Panzijian gold deposit is located in the southern of Penglai-Qixia gold metallogenic belt, Jiaodong area, Shandong, which is a typical quartz vein type of gold deposit with high gold grade. However, the source and characteristic of ore-forming fluid are still controversial. Based on the theory of mineral microscopy and microstructure of pyrite, He-Ar isotopic composition of fluid inclusions from gold-bearing pyrite at the main metallogenic stages(quartz-pyrite(sericite)and gold-quartz-polymetallic sulfide stages)in Panzijian gold deposit was measured. The results show that the abundances of ³He of fluid inclusions from gold-bearing pyrite in Panzijian gold deposit are(3.49-8.50)×10^-14 cm³ STP·g^-1, the abundances of ⁴He are(2.46-5.06)×10^-8 cm³ STP·g^-1, and ³He/⁴He ratios are 0.8R_a-1.2R_a(R_a is ³He/⁴He ratio in air, R_a=1.39×10^-6), indicating that the ore-forming fluid exhibits crust-mantle mixing characteristics dominated by enriched mantle; the abundances of ⁴⁰Ar are(1.02-2.65)×10^-7 cm³ STP·g^-1, and ⁴⁰Ar/³⁶Ar ratios are 896.3-1 724.1, which are 2-3 times of the ratio of atmospheric saturated water, but similar to the ratios of samples from mantle-derived rocks in the northeastern China, indicating that the ore-forming fluid mainly comes from enriched mantle, and the crustal fluid also participates in mineralization, because there is a certain amount of ⁴⁰Ar of crustal radioactivity in the ore-forming fluid. Therefore, it is believed that ore-forming fluid in Panzijian gold deposit is a crust-mantle mixed fluid dominated by enriched mantle fluid.

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备注/Memo

备注/Memo:

收稿日期:2019-10-22; 修回日期:2020-02-12; 网络首发日期:2020-03-20投稿网址:http:∥jese.chd.edu.cn/
基金项目:山东省地质勘探项目(鲁勘字(2018)19号); 国家自然科学基金项目(41572063); 国土资源部金矿成矿过程与资源利用重点实验室/山东省金属矿产成矿地质过程与资源利用重点实验室项目(2013003); 国家重点研发计划重点专项项目(2016YFC0601001)
作者简介:毛光周(1978-),男,甘肃甘谷人,山东科技大学副教授,工学博士,E-mail:gzmaonjunwu@163.com。

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