|本期目录/Table of Contents|

[1]陈浩男,邓小华*,何西恒,等.东天山小热泉子铜锌矿床伴生硒富集机制[J].地球科学与环境学报,2024,46(03):384-399.[doi:10.19814/j.jese.2024.02007]
　CHEN Hao-nan,DENG Xiao-hua*,HE Xi-heng,et al.Se Enrichment Mechanism of the Xiaorequanzi Copper-zinc Deposit in East Tianshan, China[J].Journal of Earth Sciences and Environment,2024,46(03):384-399.[doi:10.19814/j.jese.2024.02007]
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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:
第46卷
期数:
2024年第03期
页码:
384-399
栏目:
基础地质与矿床地质
出版日期:
2024-05-15

文章信息/Info

Title:
Se Enrichment Mechanism of the Xiaorequanzi Copper-zinc Deposit in East Tianshan, China
文章编号:
1672-6561(2024)03-0384-16
作者:
陈浩男1; 邓小华1*; 何西恒1; 阿卜力米提·艾白2
(1. 长安大学 地球科学与资源学院,陕西 西安 710054; 2. 中国科学院新疆生态与地理研究所 新疆矿产资源研究中心,新疆 乌鲁木齐 830011)
Author(s):
CHEN Hao-nan1;  DENG Xiao-hua1*;  HE Xi-heng1;  ABULIMITI Aibai2
(1. School of Earth Science and Resources, Chang'an University, Xi'an 710054, Shaanxi, China; 2. XinjiangResearch Center forMineral Resources, Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences, Urumqi 830011, Xinjiang, China)
关键词:
关键金属;  硒;  火山块状硫化物矿床;  铜锌矿;  赋存状态;  富集机制;  东天山
Keywords:
critical metals;  Se;  VMS deposit;  copper-zinc deposit;  occurrence status;  enrichment mechanism;  East Tianshan
分类号:
P611
DOI:
10.19814/j.jese.2024.02007
文献标志码:
A
摘要:
小热泉子矿床位于东天山大南湖—头苏泉岛弧带西段,是赋存于石炭纪火山-沉积建造中的火山块状硫化物(VMS)矿床。小热泉子矿床伴生硒等关键金属,但硒赋存状态及富集机制研究较为薄弱,制约了硒的综合利用。在矿床地质特征研究基础上,对不同成矿期次的矿石中硫化物开展全自动综合矿物分析、电子探针成分分析,探索小热泉子矿床中硒赋存状态和富集机制。结果表明:小热泉子矿床中硒主要呈硒独立矿物硒方铅矿或赋存于硫化物的晶格中。硒方铅矿呈半自形—他形产出,粒径多小于30 μm,包裹于喷流沉积期和热液叠加期的黄铜矿中,其Se含量(质量分数,下同)为20.25%～23.87%,平均值为22.15%,S含量为1.11%～2.61%,平均值为1.92%,Pb含量为72.49%～76.57%,平均值为74.51%,平均化学式为Pb(Se0.78 S0.17),S/Se值为0.087。不同期次黄铁矿、黄铜矿、闪锌矿等硫化物中的Se含量分别为0.07%、0.15%和0.29%,S/Se平均值分别为716、222和110。其中,喷流沉积期硫化物的Se平均含量为0.20%,S/Se平均值为212,热液叠加期硫化物的Se平均含量为0.05%,S/Se平均值为938,显示Se含量具有下降趋势。结合前人流体包裹体研究结果,小热泉子矿床中硒富集机制归因于较高温、较高氧逸度的岩浆流体环境,硒富集伴随成矿系统温度和氧逸度的降低而减弱。
Abstract:
The Xiaorequanzi deposit is a volcanic massive sulfide(VMS)deposit that occurred in Carboniferous volcano-sedimentary sequence, which is located in the western section of Dananhu-Tousuquan arc belt, East Tianshan. Critical metals such asSeare associated with Xiaorequanzi VMS deposit. However,Seoccurrencestatusand enrichment mechanismareambiguous, which restricts the comprehensive utilization ofSe.Based on previous research on the geological characteristics of ore deposits, the automated integrated mineral analysis and electron probe micro-analysis on sulfides in differentmineralizationstages of ore were used to exploreSeoccurrence status and enrichment mechanismin the Xiaorequanzi deposit. The results show that Se occurs as independent mineral, namely clausthalite, or exists in the lattice of sulfide. Clausthalite occurs in a subhedral to anhedral shape with particle size less than 30 μm, which is encapsulated in chalcopyriteof exhalative sedimentaryperiodand late hydrothermal overprinting period. The Se, S, and Pb contents of clausthalite are 20.25%-23.87%, 1.11%-2.61%, and 72.49%-76.57%, with an average of 22.15%, 1.92%, and 74.51%. The average S/Se ratio is 0.087, and the average chemical formula of clausthalite is Pb(Se0.78S0.17).The Se contents of pyrite, chalcopyrite, and sphalerite are 0.07%, 0.15%and 0.29%, and the average S/Se ratios are 716, 222 and 110. The average content of Se and S/Se ratio of sulfideineffusive deposit periodare 0.20% and 212. The average content of Se and S/Se ratio of sulfide in the late hydrothermal overprinting period are 0.05% and 938, which show a decreasing trend of Se content. Combined with the results of previous fluid inclusion studies,Se enrichmentmechanismin the Xiaorequanzi deposit is attributed to the magmatic fluid with higher temperature and higher oxygen fugacity, whileSe mineralization weakens followed by the decreasing of oxygen fugacity and temperature.

参考文献/References:

[1] 翟明国,吴福元,胡瑞忠,等.战略性关键金属矿产资源:现状与问题[J].中国科学基金,2019,33(2):106-111.
ZHAI Ming-guo,WU Fu-yuan,HU Rui-zhong,et al.Critical Metal Mineral Resources:Current Research Status and Scientific Issues[J].Bulletin of National Natural Science Foundation of China,2019,33(2):106-111.
[2]翟明国,胡 波.矿产资源国家安全、国际争夺与国家战略之思考[J].地球科学与环境学报,2021,43(1):1-11.
ZHAI Ming-guo,HU Bo.Thinking to State Security,International Competition and National Strategy of Mineral Resources[J].Journal of Earth Sciences and Environment,2021,43(1):1-11.
[3]毛景文,杨宗喜,谢桂青,等.关键矿产:国际动向与思考[J].矿床地质,2019,38(4):689-698.
MAO Jing-wen,YANG Zong-xi,XIE Gui-qing,et al.Critical Minerals:International Trends and Thinking[J].Mineral Deposits,2019,38(4):689-698.
[4]涂光炽,高振敏,胡瑞忠,等.分散元素地球化学及成矿机制[M].北京:地质出版社,2004.
TU Guang-chi,GAO Zhen-min,HU Rui-zhong,et al.Geochemistry and Metallogenic Mechanism of Dispersed Elements[M].Beijing:Geological Publishing House,2004.
[5]温汉捷,周正兵,朱传威,等.稀散金属超常富集的主要科学问题[J].岩石学报,2019,35(11):3271-3291.
WEN Han-jie,ZHOU Zhen-bing,ZHU Chuan-wei,et al.Critical Scientific Issues of Super-enrichment of Dispersed Metals[J].Acta Petrologica Sinica,2019,35(11):3271-3291.
[6]REDWOOD S D.Famous Mineral Localities:The Pacajake Selenium Mine,Potosi,Bolivia[J].Mineralogical Record,2003,34(4):339-357.
[7]陈炳翰,丁建华,叶会寿,等.中国硒矿成矿规律概要[J].矿床地质,2020,39(6):1063-1077.
CHEN Bing-han,DING Jian-hua,YE Hui-shou,et al.Metallogenic Regularity of Selenium Ore in China[J].Mineral Deposits,2020,39(6):1063-1077.
[8]刘家军,王冠智,汪 啸,等.物以“硒”为贵,人倚“硒”为福[J].矿物岩石地球化学通报,2024,https:∥link.cnki.net/urlid/52.1102.P.20240206.1350.002.
LIU Jia-jun,WANG Guan-zhi,WANG Xiao,et al.Selenium:Treasured by Nature,Embraced by Humanity[J].Bulletin of Mineralogy,Petrology and Geoche-mistry,2024,https:∥link.cnki.net/urlid/52.1102.P.20240206.1350.002.
[9]温汉捷,肖化云.硒矿物综述[J].岩石矿物学杂志,1998,17(3):69-74.
WEN Han-jie,XIAO Hua-yun.A Review of Selenium Minerals[J].Acta Petrologica et Mineralogica,1998,17(3):69-74.
[10]刘家军,翟德高,王大钊,等.Au-(Ag)-Te-Se成矿系统与成矿作用[J].地学前缘,2020,27(2):79-98.
LIU Jia-jun,ZHAI De-gao,WANG Da-zhao,et al.Classification and Mineralization of the Au-(Ag)-Te-Se Deposits[J].Earth Science Frontiers,2020,27(2):79-98.
[11]YAMAMOTO M,KASE K,TSUTSUMI M.Fractionation of Sulfur Isotopes and Selenium Between Coexisting Sulfide Minerals from the Besshi Deposit,Central Shikoku,Japan[J].Mineralium Deposita,1984,19(3):237-242.
[12]HUSTON D L,SIE S H,SUTER G F,et al.Trace Elements in Sulfide Minerals from Eastern Australian Volcanic-hosted Massive Sulfide Deposits; Part I,Proton Microprobe Analyses of Pyrite,Chalcopyrite,and Sphalerite,and Part II,Selenium Levels in Pyrite; Comparison with Delta 34 S Values and Implications for the Source of Sulfur in Volcanogenic Hydrothermal Systems[J].Economic Geology,1995,90(5):1167-1196.
[13]YESARES L,PINA R,GONZÁLEZ-JIMÉNEZ J M,et al.Distribution of Critical Metals in Evolving Pyrite from Massive Sulfide Ores of the Iberian Pyrite Belt[J].Ore Geology Reviews,2023,153:105275.
[14]TORR L,BENITES D,VALLANCE J,et al.Trace Element Geochemistry of Sphalerite and Chalcopyrite in Arc-hosted VMS Deposits[J].Journal of Geoche-mical Exploration,2022,232:106882.
[15]温汉捷,裘愉卓.拉尔玛硒-金矿床元素有机/无机结合态及硒的赋存状态研究[J].中国科学:D辑,地球科学,1999,29(5):426-432.
WEN Han-jie,QIU Yu-zhuo.Study on Organic/Inorganic Binding State of Elements and Occurrence State of Selenium in Laerma Selenium-gold Deposit[J].Science in China:Series D,Earth Sciences,1999,29(5):426-432.
[16]REVAN M K,GENC Y,MASLENNIKOV V V,et al.Mineralogy and Trace-element Geochemistry of Sulfide Minerals in Hydrothermal Chimneys from the Upper-Cretaceous VMS Deposits of the Eastern Pontide Orogenic Belt(NE Turkey)[J].Ore Geology Reviews,2014,63:129-149.
[17]KEITH M,SMITH D J,JENKIN G R T,et al.A Review of Te and Se Systematics in Hydrothermal Pyrite from Precious Metal Deposits:Insights into Ore-forming Processes[J].Ore Geology Reviews,2018,96:269-282.
[18]FRANKLIN J M,GIBSON H L,JONASSON I R,et al.Volcanogenic Massive Sulfide Deposits[J].Society ofEconomic Geologist,2005,100:523-560.
[19]VIKENTEV I.Selenium,Tellurium and Precious Me-tal Mineralogy in Uchalinsk Copper-zinc-pyritic District,the Urals[J].IOP Conference Series:Materials Science and Engineering,2016,123:012027.
[20]刘 敏,陈文明,洪 为,等.新疆东天山小热泉子铜锌(硒)矿床硒的赋存状态及硫硒比值研究[J].矿床地质,2012,31(5):1101-1110.
LIU Min,CHEN Wen-ming,HONG Wei,et al.Occurrence States of Se and S/Se Ratios Study of Xiao-requanzi Copper,Zinc(Selenium)Deposit in East Tianshan,Xinjiang[J].Mineral Deposits,2012,31(5):1101-1110.
[21]徐新煌,温春齐,茅燕石,等.新疆小热泉子铜矿床的矿石类型及其成因意义[J].矿床地质,1998,17(增):679-682.
XU Xin-huang,WEN Chun-qi,MAO Yan-shi,et al.Ore Types and Genetic Significance of Xiaorequanzi Copper Deposit,Xinjiang[J].Mineral Deposits,1998,17(S):679-682.
[22]温春齐,徐新煌,茅燕石.小热泉子铜矿床成矿过程分析[J].矿物岩石,2002,22(3):29-32.
WEN Chun-qi,XU Xin-huang,MAO Yan-shi.A Study on Ore-forming Process of the Xiaorequanzi Copper Deposit,Xinjiang[J].Journal of Mineralogy and Petrology,2002,22(3):29-32.
[23]陈文明.新疆小热泉子铜(锌)矿床同位素研究[J].地球学报,1999,20(4):349-356.
CHEN Wen-ming.A Study of the Isotopic Composition of the Xiaorequanzi Copper and Zinc Deposit in Xinjiang,China[J].Acta Geoscientica Sinica,1999,20(4):349-356.
[24]李华芹,陈富文.东疆小热泉子铜锌矿床成岩成矿作用年代学及矿床成因讨论[J].矿床地质,2002,21(增1):401-404.
LI Hua-qin,CHEN Fu-wen.Discussion on Diagenetic and Metallogenic Chronology and Genesis of Xiao-requanzi Cu-Zn Deposit in East Xinjiang[J].Mine-ral Deposits,2002,21(S1):401-404.
[25]HE X H,DENG X H,BAGAS L,et al.Geology,Geochronology,and Fluid Inclusion Studies of the Xiao-requanzi Volcanogenic Massive Sulphide Cu-ZnDeposit in the East Tianshan Terrane,China[J].Canadian Journal of Earth Sciences,2020,57(12):1392-1410.
[26]MAO Q G,WANG J B,YU M J,et al.Re-Os and U-Pb Geochronology for the Xiaorequanzi VMS Deposit in the Eastern Tianshan,NW China:Constraints on the Timing of Mineralization and Stratigraphy[J].Ore Geology Reviews,2020,122:103473.
[27]ZHANG Z X,LI N,GENG X X,et al.Fluid Inclusions,Isotopes,and Geochronology Data Constraints on the Mineralization of the Carboniferous Volcanogenic Massive Sulfide Xiaorequanzi Cu-Zn Deposit in the East Tianshan,NW China[J].Ore Geology Reviews,2021,139:104505.
[28]刘申态,吕新彪,曹晓峰,等.新疆小热泉子铜(锌)矿显微结构及稳定同位素对其成因的启示[J].矿床地质,2010,29(增1):477-478.
LIU Shen-tai,LYU Xin-biao,CAO Xiao-feng,et al.Implications of Microstructure and Stable Isotopes on Genesis of Xiaorequanzi Copper(Zinc)Deposit of Xinjiang[J].Mineral Deposits,2010,29(S1):477-478.
[29]刘申态,吕新彪,曹晓峰,等.新疆小热泉子铜(锌)矿床硫化物显微结构及稀土、微量元素研究[J].地球学报,2012,33(2):197-208.
LIU Shen-tai,LYU Xin-biao,CAO Xiao-feng,et al.A Study of Rare Earth and Trace Elements and Microstructure of Sulfide Minerals from the Xiaorequanzi Copper(Zinc)Deposit of Xinjiang[J].Acta Geoscientica Sinica,2012,33(2):197-208.
[30]温春齐,茅燕石,刘国忠.新疆小热泉子铜矿床流体包裹体特征研究[J].矿床地质,1998,17(增):1079-1082.
WEN Chun-qi,MAO Yan-shi,LIU Guo-zhong.Characteristics of Fluid Inclusions in Xiaorequanzi Copper Deposit,Xinjiang[J].Mineral Deposits,1998,17(S):1079-1082.
[31]张文东,吴湘滨,邓小华,等.东天山小热泉子矿床流体包裹体及矿床成因[J].地球科学,2018,43(9):3036-3048.
ZHANG Wen-dong,WU Xiang-bin,DENG Xiao-hua,et al.Fluid Inclusions Constraints on the Origin of the Xiaorequanzi Deposit in Eastern Tianshan[J].Earth Science,2018,43(9):3036-3048.
[32]孙 立,尚 玲.新疆小热泉子铜矿区构造特征及成矿模式[J].地质力学学报,1998,4(2):85-92.
SUN Li,SHANG Ling.StructuralFeaturesof Xiao-requanzi Copper Deposit, Xinjiang[J].Journal of Geo-mechanics,1998,4(2):85-92.
[33]李凤鸣,王宗社,侯文斌.东天山小热泉子铜矿床综合找矿模型的建立[J].新疆地质,2002,20(1):38-43.
LI Feng-ming,WANG Zong-she,HOU Wen-bin.Synthetic Prospecting Model Developed from Xiaorequanzi Copper Deposit in East Tianshan,Xinjiang[J].Xinjiang Geology,2002,20(1):38-43.
[34]王京彬,王玉往,何志军.东天山大地构造演化的成矿示踪[J].中国地质,2006,33(3):461-469.
WANG Jing-bin,WANG Yu-wang,HE Zhi-jun.Ore Deposits as a Guide to the Tectonic Evolution in the East Tianshan Mountains,NW China[J].Geology in China,2006,33(3):461-469.
[35]XIAO W J,WINDLEY B F,ALLEN M B,et al.Paleo-zoic Multiple Accretionary and Collisional Tectonics of the Chinese Tianshan Orogenic Collage[J].Gondwana Research,2013,23(4):1316-1341.
[36]秦克章,方同辉,王书来,等.东天山板块构造分区、演化与成矿地质背景研究[J].新疆地质,2002,20(4):302-308.
QIN Ke-zhang,FANG Tong-hui,WANG Shu-lai,et al.Plate Tectonics Division,Evolution and Metallogenic Settings in Eastern Tianshan Mountains,NW-China[J].Xinjiang Geology,2002,20(4):302-308.
[37]邓小华,吴昌志,吴艳爽,等.东天山印支期矿床地质特征、成因类型及成矿规律[J].地球科学与环境学报,2023,45(3):590-621.
DENG Xiao-hua,WU Chang-zhi,WU Yan-shuang,et al.Geological Characteristics,Genetic Types and Metallogenic Regularity of Indosinian Deposits in East Tianshan,China [J].Journal of Earth Sciences and Environment,2023,45(3):590-621.
[38]龙灵利,王京彬,王玉往,等.东天山古弧盆体系成矿规律与成矿模式[J].岩石学报,2019,35(10):3161-3188.
LONG Ling-li,WANG Jing-bin,WANG Yu-wang,et al.Metallogenic Regularity and Metallogenic Model of the Paleo Arc-basin System in Eastern Tianshan[J].Acta Petrologica Sinica,2019,35(10):3161-3188.
[39]张连昌,董志国,陈 博,等.东天山重要成矿区带、成矿系统与成矿规律[J].地球科学与环境学报,2021,43(1):12-35.
ZHANG Lian-chang,DONG Zhi-guo,CHEN Bo,et al.Ore-forming System and Regularity of Important Metallogenetic Belts in East Tianshan,China[J].Journal of Earth Sciences and Environment,2021,43(1):12-35.
[40]�瘙塁ENGÖR A M C,NATAL'IN B A,BURTMAN V S.Evolution of the Altaid Tectonic Collage and Palaeo-zoic Crustal Growth in Eurasia[J].Nature,1993,364:299-307.
[41]CHEN Y J,PIRAJNO F,WU G,et al.Epithermal Deposits in North Xinjiang,NW China[J].International Journal of Earth Sciences,2012,101(4):889-917.
[42]DENG J,WANG Q F.Gold Mineralization in China:Metallogenic Provinces,Deposit Types and Tectonic Framework[J].Gondwana Research,2016,36:219-274.
[43]毛景文,杨建民,韩春明,等.东天山铜金多金属矿床成矿系统和成矿地球动力学模型[J].地球科学,2002,27(4):413-424.
MAO Jing-wen,YANG Jian-min,HAN Chun-ming,et al.Metallogenic Systems of Polymetallic Copper and Gold Deposits and Related Metallogenic Geodynamic Model in Eastern Tianshan,Xinjiang[J].Earth Science,2002,27(4):413-424.
[44]邓小华,姜 晓,吴艳爽,等.东天山钨矿床时空分布、矿床类型及构造背景[J].岩石学报,2023,39(6):1557-1578.
DENG Xiao-hua,JIANG Xiao,WU Yan-shuang,et al.Temporal and Spatial Distribution,Deposit Type,and Tectonic Setting of East Tianshan Tungsten Deposit[J].Acta Petrologica Sinica,2023,39(6):1557-1578.
[45]CHEN L,WANG J B,BAGAS L,et al.Significance of Adakites in Petrogenesis of Early Silurian Magmatism at the Yudai Copper Deposit in the Kalatag District,NW China[J].Ore Geology Reviews,2017,91:780-794.
[46]SUN Y,WANG J B,LI Y C,et al.Recognition of Late Ordovician Yudai Porphyry Cu(Au,Mo)Mine-ralization in the Kalatag District,Eastern Tianshan Terrane,NW China:Constraints from Geology,Geochronology,and Petrology[J].Ore Geology Reviews,2018,100:220-236.
[47]杨富全,耿新霞,武 峰,等.新疆北部VMS矿床地质特征及成矿规律[J].地球科学,2022,47(9):3147-3173.
YANG Fu-quan,GENG Xin-xia,WU Feng,et al.VMS Deposits in the Northern Xinjiang:Geological Characteristics and Metallogeny[J].Earth Science,2022,47(9):3147-3173.
[48]CHENG X H,WANG Z J,LING M X,et al.Microstructure,Trace Element Systematics and In-situ Sulfur Isotopes of Multistage Sulfides in the Kalatag District(East Tianshan,NW China):Implications for Formation of Arc-hosted VMS Deposit[J].Ore Geology Reviews,2024,164:105762.
[49]DENG X H,MATHUR R,LI Y,et al.Copper and Zinc Isotope Variation of the VMS Mineralization in the Kalatag District,Eastern Tianshan,NW China[J].Journal of Geochemical Exploration,2019,196:8-19.
[50]DENG X H,WANG J B,SANTOSH M,et al.New 40Ar/39Ar Ages from the Kalatag District in the Eastern Tianshan,NW China:Constraints on the Timing of Cu Mineralization and Stratigraphy[J].Ore Geology Reviews,2018,100:250-262.
[51]CHENG X H,YANG F Q,ZHANG R,et al.Hydrothermal Evolution and Ore Genesis of the Hongshi Copper Deposit in the East Tianshan Orogenic Belt,Xinjiang,NW China:Constraints from Ore Geology,Fluid Inclusion Geochemistry and H-O-S-He-Ar Isotopes[J].Ore Geology Reviews,2019,109:79-100.
[52]CHENG X H,MA Y C,LING M X,et al.Petrogenesis and Metallogenic Potential of Granodiorite Porphyry in the Kalatag District,East Tianshan,NW China:Constraints from Geochronology,Mineral Geochemistry,Sr-Nd-Hf-O-S Isotopes and Sulfide Trace Elements[J].Ore Geology Reviews,2024,165:105865.
[53]王 鑫,邓小华,张 静,等.新疆东天山卡拉塔格红石铜矿床硫同位素研究[J].地质科学,2021,56(3):936-950.
WANG Xin,DENG Xiao-hua,ZHANG Jing,et al.Sulfur Isotope Characteristics of Hongshi Cu Deposit,Eastern Tianshan,NW China[J].Chinese Journal of Geology,2021,56(3):936-950.
[54]吕晓强,毛启贵,郭娜欣,等.东天山卡拉塔格地区月牙湾铜镍硫化物矿床磁黄铁矿Re-Os同位素测定及其地质意义[J].地球科学,2020,45(9):3475-3486.
LYU Xiao-qiang,MAO Qi-gui,GUO Na-xin,et al.Re-Os Isotopic Dating of Pyrrhotite from Yueyawan Cu-Ni Sulfide Deposit in Kalatage Area of East Tian-shan Mountain and Its Geological Significance[J].Earth Science,2020,45(9):3475-3486.
[55]CHENG X H,YU L J,LING M X,et al.Geochronological,Mineralogical and Geochemical Studies of Sulfide Mineralization in the Yueyawan Mafic Intrusion in the East Tianshan Orogenic Belt,NW China[J].Ore Geology Reviews,2023,152:105257.
[56]陈 磊,王京彬,邓小华,等.东天山卡拉塔格西二区铁铜矿床地质地球化学特征及成因[J].地球科学,2018,43(9):3065-3085.
CHEN Lei,WANG Jing-bin,DENG Xiao-hua,et al.Geological and Geochemical Characteristics and Genesis of Xi'erqu Fe-Cu Deposit in the Kalatag District,Eastern Tianshan,NW China[J].Earth Science,2018,43(9):3065-3085.
[57]陈寿波,黄宝强,李 琛,等.新疆东天山玉海铜矿蚀变矿化特征及SWIR勘查应用研究[J].地球科学,2018,43(9):2911-2928.
CHEN Shou-bo,HUANG Bao-qiang,LI Chen,et al.Alteration and Mineralization of the Yuhai Cu Deposit in Eastern Tianshan,Xinjiang and Applications of Short Wavelength Infra-red(SWIR)in Exploration[J].Earth Science,2018,43(9):2911-2928.
[58]XIAO B,CHEN H Y,HOLLINGS P,et al.Magmatic Evolution of the Tuwu-Yandong Porphyry Cu Belt,NW China:Constraints from Geochronology,Geochemistry and Sr-Nd-Hf Isotopes[J].Gondwana Research,2017,43:74-91.
[59]WANG Y F,CHEN H Y,BAKER M J,et al.Multiple Mineralization Events of the Paleozoic Tuwu Porphyry Copper Deposit,Eastern Tianshan:Evidence from Geology,Fluid Inclusions,Sulfur Isotopes,and Geochronology[J].Mineralium Deposita,2019,54(7):1053-1076.
[60]WANG Y H,ZHANG F F,XUE C J,et al.Geology and Genesis of the Tuwu Porphyry Cu Deposit,Xinjiang,Northwest China[J].Economic Geology,2021,116(2):471-500.
[61]何西恒,张 静,邓小华,等.东天山古生代斑岩铜矿床成矿规律和构造背景[J].岩石学报,2023,39(2):293-316.
HE Xi-heng,ZHANG Jing,DENG Xiao-hua,et al.Metallogeny and Tectonic Setting of Paleozoic Porphyry Copper Deposits in the East Tianshan[J].Acta Petrologica Sinica,2023,39(2):293-316.
[62]黎 彤,倪守斌.地球和地壳的化学元素丰度[M].北京:地质出版社,1990.
LI Tong,NI Shou-bin.The Abundance of Chemical Elements in the Earth and Crust[M].Beijing:Geological Publishing House,1990.
[63]SIMON G,ESSENE E J.Phase Relations Among Selenides,Sulfides,Tellurides,and Oxides; I,Thermodynamic Properties and Calculated Equilibria[J].Economic Geology,1996,91(7):1183-1208.
[64]SIMON G,KESLER S E,ESSENE E J.Phase Relations Among Selenides,Tellurides,and Oxides; II,Applications to Selenide-bearing Ore Deposits[J].Economic Geology,1997,92(4):468-484.
[65]LAYTON-MATTHEWS D,PETER J M,SCOTT S D,et al.Distribution,Mineralogy,and Geochemistry of Selenium in Felsic Volcanic-hosted Massive Sulfide Deposits of the Finlayson Lake District,Yukon Territory,Canada[J].Economic Geology,2008,103(1):61-88.
[66]LAYTON-MATTHEWS D,LEYBOURNE M I,PETER J M,et al.Multiple Sources of Selenium in Ancient Seafloor Hydrothermal Systems:Compositional and Se,S,and Pb Isotopic Evidence from Volcanic-hosted and Volcanic-sediment-hosted Massive Sulfide Deposits of the Finlayson Lake District,Yukon,Canada[J].Geochimica et Cosmochimica Acta,2013,117:313-331.
[67]BULLOCK L A,PEREZ M,ARMSTRONG J G,et al.Selenium and Tellurium Resources in Kisgruva Proterozoic Volcanogenic Massive Sulphide Deposit(Norway)[J].Ore Geology Reviews,2018,99:411-424.
[68]HAWLEY J E,NICHOL I.Selenium in Some Canadian Sulfides[J].Economic Geology,1959,54(4):608-628.
[69]BETHKE P M,BARTON P B.Distribution of Some Minor Elements Between Coexisting Sulfide Minerals[J].Economic Geology,1971,66(1):140-163.
[70]MARTIN A J,KEITH M,PARVAZ D B,et al.Effects of Magmatic Volatile Influx in Mafic VMS Hydrothermal Systems:Evidence from the Troodos Ophiolite,Cyprus[J].Chemical Geology,2020,531:119325.
[71]AUCLAIR G,FOUQUET Y,BOHN M.Distribution of Selenium in High-temperature Hydrothermal Sulfide Deposits at 13 Degrees North,East Pacific Rise[J].The Canadian Mineralogist,1987,25(4):577-587.
[72]WOHLGEMUTH-UEBERWASSER C C,VILJOEN F,PETERSEN S,et al.Distribution and Solubility Limits of Trace Elements in Hydrothermal Black Smoker Sulfides:An In-situ LA-ICP-MS Study[J].Geochimica et Cosmochimica Acta,2015,159:16-41.
[73]GRANT H L J,HANNINGTON M D,PETERSEN S,et al.Constraints on the Behavior of Trace Elements in the Actively-forming TAG Deposit,Mid-Atlantic Ridge,Based on LA-ICP-MS Analyses of Pyrite[J].Chemical Geology,2018,498:45-71.
[74]徐文炘.矿物包裹体中水溶气体成分的物理化学参数图解[J].矿产与地质,1991,5(3):200-206.
XU Wen-xin.Figures of Physicochemical Parameter of Water-soluble Gas Composition in Inclusions of Minerals[J].Mineral Resources and Geology,1991,5(3):200-206.
[75]李秉伦,石 岗.矿物中包裹体气体成分的物理化学参数图解[J].地球化学,1986,15(2):126-137.
LI Bing-lun,SHI Gang.Diagram of Physico-chemical Parameter for Gas Composition of Inclusions in Minerals[J].Geochimica,1986,15(2):126-137.
[76]LIU J J,ZHENG M H,LIU J M,et al.Geochemistry of the La'erma and Qiongmo Au-Se Deposits in the Western Qinling Mountains,China[J].Ore Geology Reviews,2000,17(1/2):91-111.

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备注/Memo

备注/Memo:
收稿日期:2024-02-07; 修回日期:2024-04-22
基金项目:国家自然科学基金项目(42222205,42302108); 第三次新疆综合科学考察项目(2022xjkk1301); 新疆维吾尔自治区重点研发专项项目(2023B03015)
*通信作者:邓小华(1984-),男,四川中江人,教授,博士研究生导师,理学博士,E-mail:dxh198411@126.com。
通信作者:阿卜力米提·艾白(1991-),男,新疆和田人,助理研究员,理学博士,E-mail:ablimitab@ms.xjb.ac.cn。
更新日期/Last Update: 2024-05-30