|本期目录/Table of Contents|

[1]朱雷,王月辉,杨永才,等.不同填充方法色谱柱分离原油及沥青 砂岩抽提物的饱和烃地球化学特征[J].地球科学与环境学报,2008,30(04):389-395.
　ZHU Lei,WANG Yue-hui,YANG Yong-cai,et al.Geochemical Characteristics of the Saturate Hydrocarbon of Crude Oils and Bituminous Sandstone Extracts Separated by Chromatographic Columns with Different Packed Methods[J].Journal of Earth Sciences and Environment,2008,30(04):389-395.
点击复制

不同填充方法色谱柱分离原油及沥青 砂岩抽提物的饱和烃地球化学特征(PDF)
分享到：

《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:
第30卷
期数:
2008年第04期
页码:
389-395
栏目:
基础地质与矿产地质
出版日期:
2008-12-20

文章信息/Info

Title:
Geochemical Characteristics of the Saturate Hydrocarbon of Crude Oils and Bituminous Sandstone Extracts Separated by Chromatographic Columns with Different Packed Methods
作者:
朱雷1; 王月辉1; 杨永才1; 秦黎明1; 张宏友2
1.中国石油大学油气资源与探测国家重点实验室,北京102249; 2.中国海洋石油有限公司天津分公司技术部,天津300452
Author(s):
ZHU Lei1; WANG Yue-hui1; YANG Yong-cai1; QIN Li-ming1; ZHANG Hong-you2
1.State Key Laboratory for Petroleum Resource and Prospecting, China University o f Petroleum, Beijing 102249, China; 2.Technical Department o f Tianjin Branch o f China National Offshore Oil Corporation Limited, Tianjin 300452, China)
关键词:
色谱柱; 氧化铝; 硅胶; 族组成; 生物标志物
Keywords:
chromatographic column;  alumina;  silica gel;  fractions;  biomarkers
分类号:
P618.130.1
DOI:
-
文献标志码:
A
摘要:
采用柱色谱分离方法,分别以氧化铝(5g)、上部为氧化铝下部为硅胶(3g∶2g)、上部为硅胶下部为氧化 铝(3g∶2g)和硅胶(5g)4种填充方法对原油和沥青砂岩抽提物进行族组成分析,对其饱和烃馏分进行气相色 谱-质谱分析,对比剖析了饱和烃生物标志物组成特征。结果表明:这4种不同的填充方法对类异戊间二烯型烷 烃、藿烷、规则甾烷等生物标志物的分子组成影响一般均较小,但对于高碳数正构烷烃和重排甾烷等化合物的影 响则较明显。
Abstract:
The fractions of crude oil and bituminous sandstone extract were separated by chromatographic columns with four packed methods,that is,respectively,alumina(5 g), alumina(3 g)at the top and silica gel(2 g)in the bottom, silica gel(3 g)at the top and alumina(2 g)in the bottom, silica(5 g). The saturated hydrocarbons were analyzed by gas chromatography-mass spectrometry, and the compositions of biomarkers were compared. The results show that the four column chromatographic methods yield slight affection to the distributions of isoprenoid alkanes, tricyclic terpanes, hopanes and regular steranes in the saturated hydrocarbon fraction, but apparent affection to the occurrence of high molecular weight n-alkanes and diasteranes.

参考文献/References:

[1] SY/ T 5119 —1995 , 岩石可溶有机物和原油 族组分柱 层析分 离方法[S] .
[2] Later D W, Lee M L , Bart le K D, et al.Chemical C lass S eparation and Charact eriz at ion of Organi c Compounds in S ynthetic Fuels[J] .Analyt ical Chemi st ry , 1981 , 53(11):1612- 1620 .
[3] 李勇志 , 邓先梁 , 俞惟乐 .对氧化铝和硅胶分离重 质油组分性 能的新认识[J] .石油学报 , 1998 , 14(2):75-80 .
[4] 李勇志 , 邓先梁 , 俞惟乐 .氧化铝对长链正构烷烃 的吸附性能 [J] .科学通报 , 1998 , 43(1):53-55 . 394 地球科学与环境学报 第 30 卷
[5] Jiang C , Li M , van Duin A C T .Inadequate S eparation of Satu rat e and Monoaromat ic Hy drocarb ons in C rude Oi ls an d Rock Ex t racts by Alumina Colum n Ch romatography[J] .O rganic Geochemi st ry , 2000 , 31(7/ 8):751-756 .
[6] 别道哲 , 曹建平 , 郑伦举 .原油及生油岩族组 分旋转薄层色谱 分析[J] .石油试验地质 , 1999 , 21(2):184-187 .
[7] 徐世平 , 孙永革 .一种适 用于沉积 有机质族 组分分离 的微型 柱色谱法[J] .地球化学 , 2006 , 35(6):681-688 .
[8] 季 东 , 关 平 , 肖玉雄 , 等 .原油极 性分离法 及其对 解释原 油碳同位素特征的作用[J] .天然气 地球科 学 , 2007 , 18(3): 447-453 .
[9] 孟志强 , 秦 鹏 , 刘景伟 , 等 .有机抽 提物族组 分小柱 状色谱 分离[J] .化学世界 , 2006 , 8(5):271-272 .
[10] Didyk B M , Sim oneit B R T , Brassell S C , et al.Organi c Geochemi cal Indicat ors of Palaeoenvi ronment al C on di ti on s of S ediment ation[J] .Nature , 1978 , 272 :216-222 .
[11] Peters K E , Moldow an J M .Ef fect s of Source , Thermal Maturit y , and Biodegradati on on the Di st ribut ion and Isomeri zat ion of H om ohopanes in Pet roleum[J] .Organic Geochemist ry , 1991 , 17(1):47-61 .
[12] Hughes W B , H olba A G , Dzou L I .The Rati os of Dib enz othioph ene t o Ph enanthrene and Pris tane to Phyt ane as Indicat ors of Depositi onal Environment and Li th ol ogy of Pet roleum Source Rocks [J] .Geochimi ca et C osmochimi ca Act a, 1995 , 59(17):3581-3598 .
[13] Peters K E , Moldow an J M .Th e Biomarker Guide :Int erpret ing Molecular Fos sils in Pet roleum and Anci en t Sedim en ts [M] .New Jersey :Prenti ce H all , 1993 .
[14] Pet ers K E , Wal ters C C , M oldow an J M .T he Biomarker Guide:Biomarkers an d Isot opes in the E nvi ronment and Hum an Hi st ory[M] .Combidge :Cambridge Universit y Press , 2005 .
[15] Moldow an J M , Sei fert W K , Gallegos E J .Relati on ship betw een Pet roleum Comp osi ti on and Depositi onal En vi ronm en t of Pet rol eum Sou rce Rocks[J] .The Am erican Associ at ion of Pet roleum Geologis t s Bul let in , 1985 , 69(8):1255-1268 .
[16] Fu J M , S heng G R, Peng P A , et al .Peculiarit ies of Salt Lak e S ediment s as Pot en tial Source Rock s in C hina[J] .Organic Geochemist ry , 1986 , 10(1/ 3):119-126 .
[17] Seif ert W K , Moldowan J M .The Ef f ect of T hermal St ress on S ou rce Rock Qualit y as M easured by Hopane St ereochemi st ry[J] .Physics and Chemis try of the Earth , 1980 , 12 : 229-237 .
[18] Ti ssot B P , Wel te D H .Pet roleum Formati on and Occu rrence [M] .Berlin :Sp ringer-Verlag , 1978 .
[19] Volkm an J K .A Revi ew of S terol Markers for M arin e and T er rigenous Organic Mat ter [J] .Organic Geochemist ry , 1986 , 9(2):83-99 .
[20] Cz ochanska Z ,Gilbert T D , Philp R P , et al.Geochemi cal Applicat ion of St erane and T ri terpane Biomarkers to a Des cript ion of Oil s f rom the Taranaki Basin in New Zealand[J] .Organic Geochemis t ry , 1988 , 12(2):123-135 .
[21] T en H aven H L , de Leeuw J W, Peakman T M , et al.Anomali es in S t eroid and H opani od Matu ri ty Indi ces[J] .Geochimica et Cosm ochimi ca Act a , 1986 , 50(5):853-855 .
[22] 张枝焕 , 关 强 .新疆 三塘湖盆 地二叠系 油源分析[J] .石油 试验地质 , 1998 , 20(2):174-181 .
[23] 常象春 , 王明镇 , 韩作振 .试论适合叠合盆地的油 源对比方法 [J] .地球科学与环境学报 , 2004 , 26(4):32-36 .

相似文献/References:

备注/Memo

备注/Memo:
收稿日期:2008-02-26
基金项目:国家重点基础研究发展计划项目(2006CB202303)
作者简介:朱雷(1969-),男,上海人,试验师,从事试验地球化学研究。E-mail:zhuleidike@126.com
更新日期/Last Update: 2008-12-20