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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第41卷

期数:

2019年第02期

页码:

197-208

栏目:

基础地质与矿产地质

出版日期:

2019-03-15

文章信息/Info

Title:

Geochemical and Li-bearing Characteristics of Fluids from Borehole ZK001 in Huangjinkou Anticline of the Northeastern Sichuan, China

文章编号:

1672-6561(2019)02-0197-12

作者:

高娟琴¹; 2; 于扬^1*; 仲佳爱¹; 刘铸³; 张塞¹; 2; 庞博³

(1.中国地质科学院矿产资源研究所 自然资源部成矿作用与资源评价重点实验室,北京 100037; 2.中国地质大学(北京)地球科学与资源学院,北京 100083; 3.四川省地质矿产勘查开发局405地质队,四川 都江堰 611830)

Author(s):

GAO Juan-qin¹; 2;  YU Yang^1*;  ZHONG Jia-ai¹;  LIU Zhu³;  ZHANG Sai¹; 2;  PANG Bo³

(1. MNR Key Laboratory of Metallogeny and Mineral Resource Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China; 2. School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China; 3. No.405 Geological Party, Sichuan Bureauof Geology and Mineral Exploration and Development, Dujiangyan 611830, Sichuan, China)

关键词:

地球化学;  科学钻探;  深部卤水;  随钻流体;  富锂;  卤水资源;  水化学特征;  四川

Keywords:

geochemistry;  scientific drilling;  deep brine;  fluid during drilling;  Li-rich;  brine resource;  hydrochemical characteristic;  Sichuan

分类号:

P592; P595

DOI:

-

文献标志码:

A

摘要:

伴随着中国高镁低锂老卤溶液提纯碳酸锂的关键技术取得突破,卤水提锂日益受到重视。深地资源勘查开发专项中的锂能源金属矿产基地深部探测技术示范项目在川东北宣汉地区布置了3 227 m深钻孔(ZK001),主要研究目的是探讨深部是否存在富锂卤水。随钻流体(常用钻探循环泥浆气体)分析是常规井口流体实时监测的主要手段,但因Li化学性质活泼,气体组分难以全面反映Li的富集浓度,故本次对钻孔流体(包含深部卤水、随钻流体、钻孔洗井水)及钻孔周边地表水、地下水进行了取样分析,首次获得了川东北黄金口ZK001钻孔流体组分特征,初步归纳了钻孔流体中Li及其他主要组分的变化规律。结果表明:川东北黄金口各类型水样品Li质量浓度从大到小依次为深部卤水、钻孔洗井水、随钻流体、地下水、地表水; 比较ZK001钻孔随钻流体组分随深度变化特征,发现0～500 m深度随钻流体Li质量浓度相对较高,Mg/Li值较低,且流体Li质量浓度异常与深度成正比,Mg/Li值与深度成反比; ZK001钻孔3 000 m深度处采集的黄色卤水Na、K、Rb、Sr等有用组分达到卤水工业品位,Li质量浓度(10 556 μg·L^-1)接近边界品位(24 599 μg·L^-1)的一半,Mg/Li值为33.92。上述钻孔流体特征将为下一步钻探工程布置提供科学支撑。

Abstract:

Since great breakthrough was made in purifying lithium carbonate from brine with high content of magnesium and low content of lithium, extracting lithium from brine has obtained increasing attention in China. Potassium-rich brine in the northeastern Sichuan contains many kinds of rare metals such as lithium which is urgently demanded in strategic emerging industries, while associated lithium resources of potassium-bearing brine are rarely considered in previous studies. A borehole(ZK001)with the depth of 3 227 m was arranged in deep exploration project in Xuanhan area of the northeastern Sichuan, of which the main goal is to investigate lithium-bearing brines in the deep. Analysis of fluids during drilling(conventional circulating drilling gas)is a main method of conventional real-time monitoring of wellhead fluids. As a result of lithium’s active property, it is difficult to reveal enrichment features of lithium by gas component only. Fluids of borehole ZK001(include deep brine, fluids during drilling, drilling-washing water), surface water and groundwater around borehole ZK001 were collected and analyzed; the characteristics of fluids during drilling were obtained for the first time; and the vertical variations of lithium and other components of drilling fluids in borehole ZK001 were summarized. The lithium concentrations in different types of water around borehole ZK001 show a rule that deep brine, drilling-washing water, fluids during drilling, groundwater, and surface water in descending order. By comparing the profile characteristics of the composition of fluids during drilling in borehole ZK001, it is discovered that lithium concentration of fluids during drilling in the depth of 0-500 m is relatively high while the ratio of Mg/Li is low. It is revealed that lithium concentration of fluids during drilling is proportional to the depth, and the ratio of Mg/Li is inversely proportional to depth. Lithium concentration of yellow brine collected at the depth of 3 000 m from borehole ZK001 is 10 556 μg·L^-1(the ratio of Mg/Li is 33.92), which almost reaches the half of the cut-off grade(24 599 μg·L^-1). In addition, Na, K, Rb, Sr components of the yellow brine from borehole ZK001 reach industrial grade. These features of fluids from borehole ZK001 will provide scientific support for future arrangement in drilling engineering.

参考文献/References:

[1] 王登红,王瑞江,付小方,等.对能源金属矿产资源基地调查评价基本问题的探讨:以四川甲基卡大型锂矿基地为例[J].地球学报,2016,37(4):471-480.
WANG Deng-hong,WANG Rui-jiang,FU Xiao-fang,et al.Discussion on the Major Problems Related to Geological Investigation and Assessment for Energy Metal Resources Base:A Case Study of the Jiajika Large Lithium Mineral Resource Base[J].Acta Geoscientica Sinica,2016,37(4):471-480.
[2] 王登红,王成辉,孙 艳,等.我国锂铍钽矿床调查研究进展及相关问题简述[J].中国地质调查,2017,4(5):1-8.
WANG Deng-hong,WANG Cheng-hui,SUN Yan,et al.New Progresses and Discussion on the Survey and Research of Li,Be,Ta Ore Deposits in China[J].Geological Survey of China,2017,4(5):1-8.
[3] 刘丽君,王登红,刘喜方,等.国内外锂矿主要类型、分布特点及勘查开发现状[J].中国地质,2017,44(2):263-278.
LIU Li-jun,WANG Deng-hong,LIU Xi-fang,et al.The Main Types,Distribution Features and Present Situation of Exploration and Development for Domestic and Foreign Lithium Mine[J].Geology in China,2017,44(2):263-278.
[4] 王登红,孙 艳,刘喜方,等.锂能源金属矿产深部探测技术方法与找矿方向[J].中国地质调查,2018,5(1):1-9.
WANG Deng-hong,SUN Yan,LIU Xi-fang,et al.Deep Exploration Technology and Prospecting Direction for Lithium Energy Metal[J].Geological Survey of China,2018,5(1):1-9.
[5] 赵元艺.中国盐湖锂资源及其开发进程[J].矿床地质,2003,22(1):99-106.
ZHAO Yuan-yi.Saline Lake Lithium Resources of China and Its Exploitation[J].Mineral Deposits,2003,22(1):99-106.
[6] 刘向磊,钟 辉,唐中杰.盐湖卤水提锂工艺技术现状及存在的问题[J].无机盐工业,2009,41(6):4-6.
LIU Xiang-lei,ZHONG Hui,TANG Zhong-jie.Current Status and Existing Problems of Lithium Extraction Technology from Salt Lake[J].Inorganic Chemicals Industry,2009,41(6):4-6.
[7] 汪镜亮.卤水锂资源提锂现状[J].化工矿物与加工,1999,28(12):1-5.
WANG Jing-liang.The Present Status of Lithium Extraction from Li-bearing Brines[J].Industrial Minerals and Processing,1999,28(12):1-5.
[8] 赵元艺,郑绵平,卜令忠,等.西藏碳酸盐型盐湖卤水锂盐提取盐田工艺研究[J].海湖盐与化工,2005,34(2):1-6.
ZHAO Yuan-yi,ZHENG Mian-ping,BU Ling-zhong,et al.Study on Salt Pan Technology of Lithium Salt Extracting from Carbonate-type Saline Lakes,Tibet[J].Journal of Salt Science and Chemical Industry,2005,34(2):1-6.
[9] 高 峰,郑绵平,乜 贞,等.盐湖卤水锂资源及其开发进展[J].地球学报,2011,32(4):483-492.
GAO Feng,ZHENG Mian-ping,MIE Zhen,et al.Brine Lithium Resource in the Salt Lake and Advances in Its Exploitation[J].Acta Geoscientica Sinica,2011,32(4):483-492.
[10] 林耀庭,姚有成,康正华,等.四川宣达盐盆富钾富矿卤水地球化学特征及资源意义研究[J].盐湖研究,2004,12(1):8-18.
LIN Yao-ting,YAO You-cheng,KANG Zheng-hua,et al.Study on the Geochemical Characteristics and Resource Significance of the Highly Mineralized Potassium-rich Brine in the Xuanda Salt Basin,Sichuan[J].Journal of Salt Lake Research,2004,12(1):8-18.
[11] 林耀庭.四川盆地地下卤水资源优势及综合开发前景[J].盐湖研究,2006,14(4):1-8.
LIN Yao-ting.Resource Advantages of the Underground Brines of Sichuan Basin and the Outlook of Their Comprehensive Exploitation[J].Journal of Salt Lake Research,2006,14(4):1-8.
[12] 仲佳爱,郑绵平,唐学渊,等.川东北黄金口背斜三叠系深部杂卤石特征及成因探讨[J].矿床地质,2018,37(1):81-90.
ZHONG Jia-ai,ZHENG Mian-ping,TANG Xue-yuan,et al.Sedimentary Characteristics and Genetic Study of Deep Polyhalite in Huangjinkou Anticline of Northeast Sichuan[J].Mineral Deposits,2018,37(1):81-90.
[13] 段德昭.宣汉黄金口勘探区须家河组的砂岩岩石学特征[J].河北工程大学学报(自然科学版),2012,29(4):58-61.
DUAN De-zhao.The Sandstone Petrology of Xujiahe Formation in Huangjinkou Exploration Area,Xuanhan County,Sichuan Province[J].Journal of Hebei University of Engineering(Natural Science Edition),2012,29(4):58-61.
[14] MOLLER P,WEISE S M,ALTHAUS E,et al.Paleofluids and Recent Fluids in the Upper Continental Crust:Results from the German Continental Deep Drilling Program(KTB)[J].Journal of Geophysical Research:Solid Earth,1997,102(B8):18233-18254.
[15] BODEN A,ERIKSSON K G.Deep Drilling in Crystalline Bedrock[M].Berlin:Springer-Verlag,1988.
[16] FABER E.Origin of Hydrocarbon Gases in the Pump-test of the KTB Pilot Well[J].Scientific Drilling,1995,5(3):123-128.
[17] 许志琴.中国大陆科学钻探工程的科学目标及初步成果[J].岩石学报,2004,20(1):1-8.
XU Zhi-qin.The Scientific Goals and Investigation Progresses of the Chinese Continental Scientific Project[J].Acta Petrologica Sinca,2004,20(1):1-8.
[18] 汪蕴璞,王焕夫,王东升.深层卤水形成问题及其研究方法[M].北京:地质出版社,1982.
WANG Yun-pu,WANG Huan-fu,WANG Dong-sheng.The Research Method and Formation Problem of Deep Brine[M].Beijing:Geological Publishing House,1982.
[19] GRUBER P W,MEDINA P A,KEOLEIAN G A,et al.Global Lithium Availability:A Constraint for Electric Vehicles?[J].Journal of Industrial Ecology,2011,15(5):760-775.
[20] 唐力君,王晓春,王 健,等.科学钻探工程中的随钻实时流体分析[J].岩矿测试,2011,30(5):637-643.
TANG Li-jun,WANG Xiao-chun,WANG Jian,et al.Real-time Fluid Analysis in the Scientific Drilling Project[J].Rock and Mineral Analysis,2011,30(5):637-643.
[21] 唐力君,劳昌玲,范 凡,等.WFSD-4孔深部流体分析和多组分地球化学特征[J].地球学报,2015,36(4):434-440.
TANG Li-jun,LAO Chang-ling,FAN Fan,et al.Fluid Analysis and Multi-component Geochemical Features in the Depth of Drill Hole WFSD-4[J].Acta Geoscientica Sinica,2015,36(4):434-440.
[22] 杨立中.论四川盆地地下卤水资源开发利用的现状及对策[J].四川地质学报,1992,12(3):227-231.
YANG Li-zhong.On the Present Situation of the Exploitation of Underground Brine in the Sichuan Basin and Its Countermeasure[J].Acta Geologica Sichuan,1992,12(3):227-231.
[23] 林耀庭,何金权,王田丁,等.四川盆地中三叠统成盐贫富钾卤水地球化学特征及勘查开发前景研究[J].化工矿产地质,2002,24(2):72-84.
LIN Yao-ting,HE Jin-quan,WANG Tian-ding,et al.Geochemical Characteristics of Potassium-rich Brine in Middle Triassic Chengdu Salt Basin of Sichuan Basin and Its Prospects for Brine Tapping[J].Geology of Chemical Minerals,2002,24(2):72-84.
[24] 马生凤,温宏利,许俊玉,等.电感耦合等离子体质谱法测定地下水中44个元素[J].岩矿测试,2010,29(5):552-556.
MA Sheng-feng,WEN Hong-li,XU Jun-yu,et al.Determination of 44 Elements in Groundwater by Inductively Coupled Plasma-mass Spectrometry[J].Rock and Mineral Analysis,2010,29(5):552-556.
[25] GB/T 14506.30—2010,硅酸盐岩岩石化学分析方法第30部分:44个元素量测定[S].
GB/T 14506.30—2010,Methods for Chemical Analysis of Silicate Rocks Part 30:Determination of 44 Elements[S].
[26] 张宝全.柴达木盆地盐湖卤水提锂研究概况[J].海湖盐与化工,2000,29(4):9-13.
ZHANG Bao-quan.Survey of Lithium Extraction from Salt Lake Brine in Qaidam Basin[J].Journal of Salt Science and Chemical Industry,2000,29(4):9-13.
[27] 韩凤清.青藏高原盐湖 Li 地球化学[J].盐湖研究,2001,9(1):55-61.
HAN Feng-qing.The Geochemistry of Lithium in Salt Lake on Qinghai-Tibetan Plateau[J].Journal of Salt Lake Research,2001,9(1):55-61.
[28] 伍 倩,刘喜方,郑绵平,等.我国盐湖锂资源开发现状,存在问题及对策[J].现代化工,2017,37(5):1-5.
WU Qian,LIU Xi-fang,ZHENG Mian-ping,et al.Present Situation,Existing Problems and Countermeasures of Development of Salt Lake Lithium Resources in China[J].Modern Chemical Industry,2017,37(5):1-5.
[29] 陈小炜,周恳恳,牟传龙,等.浅析四川盆地典型储卤构造地下卤水型锂资源潜力[J].轻金属,2016(10):7-11.
CHEN Xiao-wei,ZHOU Ken-ken,MU Chuan-long,et al.Analysis of the Potential of Underground Brine Lithium Resource in the Typical Brine-reserve Structures in Sichuan Basin[J].Light Metals,2016(10):7-11.
[30] 詹涵钰,马红熳,武文辉,等.四川自贡地区地下卤水锂矿化特征及靶区预测[J].中国地质调查,2018,5(4):17-24.
ZHAN Han-yu,MA Hong-man,WU Wen-hui,et al.Mineralization Characteristics and Target Area Prediction of Underground Brine Lithium Mine in Zigong Area,Sichuan Province[J].Geological Survey of China,2018,5(4):17-24.
[31] 徐国盛,陈美玲,刘 为,等.川西地区雷口坡组岩相古地理与富钾卤水预测[J].矿床地质,2012,31(2):309-322.
XU Guo-sheng,CHEN Mei-ling,LIU Wei,et al.Lithofacies Palaeogeography and Forecast of Potassium-rich Brine of Leikoupo Formation in Western Sichuan[J].Mineral Deposits,2012,31(2):309-322.
[32] 周 游.四川盆地三叠纪富钾卤水资源量评价方法[D].成都:成都理工大学,2014.
ZHOU You.Study of Potassium-rich Brine Resources Evaluation Methods in Sichuan Basin[D].Chengdu:Chengdu University of Technology,2014.
[33] 寇文杰.地下水化学分类方法的思考[J].西部资源,2012(5):108-109.
KOU Wen-jie.Thinking on Groundwater Chemical Classification Methods[J].Western Resources,2012(5):108-109.
[34] 宋鹤彬.川西成都盐盆平落4井富钾硼溴浓卤水水化学同位素地球化学特征及形成机制[J].地球学报,1997,18(3):282-289.
SONG He-bin.The Hydrochemistry and Isotope Geochemistry of Brines Which Enrich in Potash,Boron and Bromine in Well Pingluo4 of Chengdu Sold Basin[J].Acta Geoscientica Sinica,1997,18(3):282-289.
[35] 《矿产资源工业要求手册》编委会.矿产资源工业要求手册[M].北京:地质出版社,2014.
Editorial Committee of Manual of Mineral Resources Industry Requirements.Manual of Mineral Resources Industry Requirements[M].Beijing:Geological Publishing House,2014.
[36] 陈郁华.黄海水25 ℃恒温蒸发时的析盐序列及某些微量元素的分布规律[J].地质学报,1983,57(4):379-390.
CHEN Yu-hua.Sequence of Salt Separation and Distribution Regularity of Some Trace Elements During Isothermal Evaporation(25 ℃)of the Huanghai Sea Water[J].Acta Geologica Sinica,1983,57(4):379-390.
[37] 迟清华,鄢明才.应用地球化学元素丰度数据手册[M].北京:地质出版社,2007.
CHI Qing-hua,YAN Ming-cai.Manual of Element Ab-undance Data in Applied Geochemistry[M].Beijing:Geological Publishing House,2007.

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[7]张嘉升,潘爱芳,樊会民,等.陕西柞水地区金盆梁金矿区水系沉积物地球化学特征与找矿方向[J].地球科学与环境学报,2014,36(04):55.
　ZHANG Jia-sheng,PAN Ai-fang,FAN Hui-min,et al.Geochemical Characteristics of Stream Sediment in Jinpenliang Gold Mining Area of ZhashuiArea, Shaanxi and Its Prospecting Direction[J].Journal of Earth Sciences and Environment,2014,36(02):55.
[8]曹军,钟宁宁,邓运华,等.下刚果盆地海相烃源岩地球化学特征、成因及其发育的控制因素[J].地球科学与环境学报,2014,36(04):87.
　CAO Jun,ZHONG Ning-ning,DENG Yun-hua,et al.Geochemical Characteristics, Origin and Factors Controlling Formation of Marine Source Rock in Lower Congo Basin[J].Journal of Earth Sciences and Environment,2014,36(02):87.
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　JIANG Chang-yi,WANG Zi-xi,DU Wei.Geochemical Characteristics of Nanbeigou Intrusion in the Northern Margin of Qaidam Massif and Its Prospecting Potential[J].Journal of Earth Sciences and Environment,2015,37(02):12.
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　LIU Cheng-lin,XU Yun,MA Yin-sheng,et al.Geochemical Characteristics and Origin of Anthraxolite of Tanjianshan Group in the Northern of Qaidam Basin[J].Journal of Earth Sciences and Environment,2015,37(02):85.

备注/Memo

备注/Memo:

收稿日期:2018-11-08; 修回日期:2018-12-12 投稿网址:http://jese.chd.edu.cn/
基金项目:国家重点研发计划项目(2017YFC0602705); 中国地质调查局地质调查项目(DD20160055)
作者简介:高娟琴(1993-),女,山西临汾人,中国地质大学(北京)理学博士研究生,E-mail:gaojuanqinmail@sina.com。
*通讯作者:于 扬(1982-),女,黑龙江鹤岗人,副研究员,理学博士,E-mail:yuyang_cags@sina.com。

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更新日期/Last Update: 2019-02-28