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《地球科学与环境学报》[ISSN:1672-6561/CN:61-1423/P]

卷:

第42卷

期数:

2020年第05期

页码:

668-677

栏目:

水资源与环境

出版日期:

2020-09-15

文章信息/Info

Title:

Hydrochemical Characteristics and Genesis of High-fluorine Shallow Groundwater in Yanggu Area of the Northwestern Shandong, China

文章编号:

1672-6561(2020)05-0668-10

作者:

郝启勇¹; 2; 徐晓天¹; 张心彬¹; 周 来³

1. 山东省煤田地质规划勘察研究院,山东 济南 250104; 2. 山东地质实验中心,山东 济南 250100; 3. 中国矿业大学 环境与测绘学院,江苏 徐州 221116

Author(s):

HAO Qi-yong¹; 2;  XU Xiao-tian¹;  ZHANG Xin-bin¹;  ZHOU Lai³

1. Exploration Research Institute of Shandong Coal Field Geology Bureau, Jinan 250104, Shandong, China; 2. Shangdong Research Center for Geoanalysis, Jinan 250100, Shandong, China; 3. School of Environment and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China

关键词:

浅层地下水;  水化学;  氟;  成因类型;  古河床高地;  离子交替吸附作用;  水文地球化学;  山东

Keywords:

shallow groundwater;  hydrochemistry;  fluorine;  genetic type;  highland of ancient river bed;  alternate and adsorption of ion;  hydrogeochemistry;  Shandong

分类号:

P641.3; X523

DOI:

10.19814/j.jese.2020.04033

文献标志码:

A

摘要:

鲁西北地区是饮水型氟中毒较为突出的地区。选取鲁西北阳谷地区为研究对象,以水文地质调查和取样分析为工作基础,对浅层地下水采用多元统计分析法、地理信息空间分析法及Piper三线图探究了高氟地下水化学特征和赋存特征,结合饱和指数、Gibbs图和氯碱指数以及氟在土壤与地下水的相关关系,从溶解与沉淀平衡、蒸发浓缩和离子交替吸附作用方面分析了氟的来源和高氟地下水成因。结果表明:阳谷地区F^-浓度大于或等于2 mg·L^-1的高氟水分布于地形较高的古河床高地; 地下水F^-浓度由低到高,阳离子则由Ca²⁺、Mg²⁺向Na⁺转变,阴离子则由SO^2-₄和Cl^-向HCO^-₃转变; 阴、阳离子浓度随F^-浓度变化显示不同的规律性,且在F^-浓度大于或等于4 mg·L^-1的高氟水中,这种规律性变化更为明显; 土壤和地下水呈碱性、高HCO^-₃的化学特征以及区域地下水受蒸发浓缩作用影响是高氟水形成的水文地球化学背景条件; 方解石、萤石和石膏的溶解与沉淀平衡以及阴、阳离子交替吸附作用是高氟水形成和分布的主控因素。

Abstract:

The northwestern Shandong is an area of drinking water fluorosis. Yanggu area in the northwestern Shandong was selected as the research object. Based on the hydrogeological survey and sampling analysis, the hydrochemical and occurrence characteristics of high-fluorine groundwater were studied by using multivariate statistical analysis, geographic information spatial analysis and Piper trilinear diagram. Combining with saturation index, Gibbs diagram, chlor-alkali index and the correlation of fluorine between soil and groundwater, the equilibrium of dissolution and precipitation, evaporation and concentration, alternating adsorption of ions were studied to find the source of fluorine and the genesis of high-fluorine groundwater. The results show that the high-fluorine groundwater with F^- concentration more than or equal to 2 mg·L^-1 in Yanggu area is distributed in the highland of ancient river bed with high topography; F^- concentration in groundwater changes from low to high, and then, the cation changes from Ca²⁺, Mg²⁺to Na⁺, and the anion changes from SO^2-₄ and Cl^- to HCO^-₃; the concentrations of cation and anion show different regularity with F^- concentration, and the variation is more obvious when F^- concentration is more than or equal to 4 mg·L^-1; the chemical characteristics of soil and groundwater are alkaline and high HCO^-₃, and the regional groundwater is affected by evaporation, which is the hydrogeochemical background condition for the formation of high-fluorine groundwater; the dissolution and precipitation balance of calcite, fluorite and gypsum, and the alternate adsorption of anion and cation, are the main factors controlling the formation and distribution of high-fluorine groundwater.

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备注/Memo

备注/Memo:

收稿日期:2020-04-18; 修回日期:2020-08-25; 网络首发日期:2020-09-30投稿网址:http:∥jese.chd.edu.cn/
基金项目:国家自然科学基金项目(41572218); 山东省地质勘查项目(鲁勘字[2013]143号)
作者简介:郝启勇(1979-),男,山西汾阳人,山东省煤田地质规划勘察研究院高级工程师,E-mail:haoqiyong@163.com。

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更新日期/Last Update: 2020-09-20